• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

用于预测润湿性变化的沥青质与固体表面相互作用的分子水平表征

Molecular level characterization of interactions between asphaltene and solid surface for forecasting changes in wettability.

作者信息

Bastami Dariush, Shahrabadi Abbas, Naderi Hassan, Taghikhani Vahid, Taheri-Shakib Jaber

机构信息

Department of Chemical and Petroleum Engineering, Sharif University of Technology, Tehran, Iran.

Petroleum Engineering Division, Research Institute of Petroleum Industry, Tehran, Iran.

出版信息

Sci Rep. 2025 Aug 4;15(1):28394. doi: 10.1038/s41598-025-12599-y.

DOI:10.1038/s41598-025-12599-y
PMID:40759995
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12322175/
Abstract

This research presents a new experimental approach designed to investigate the asphaltene-solid surface molecular interactions, and how these interactions affect changes in wettability. The methodology's impact was assessed by altering the calcite surfaces wettability, evaluated through contact angle measurements. Furthermore, the properties of the asphaltene fractions were analyzed using techniques such as Field Emission Scanning Electron Microscopy, elemental analysis, Fourier Transform Infrared Spectroscopy, and zeta potential measurements. Experiments were carried out on four different Iranian oil samples, named A, B, F, and G. Results indicated that the B-Sample significantly increased the oil-wetting properties of the surface compared to other samples. Based on Fractionation studies, Whole asphaltene was separated into four sub-fractions called [Formula: see text], [Formula: see text], [Formula: see text], and [Formula: see text]. After a toluene wash, 24.16% of asphaltenes from the B-Sample remained adhered to the calcite surface. Wetting properties are related to the polarity of the asphaltene attached to the surface not the polarity of the Whole asphaltene. This indicates that the surface properties influenced by asphaltenes are not solely due to their inherent polarity but also to their interaction with the surface. Moreover, there appears to be a correlation between wettability and zeta potential, linked to the [Formula: see text] fraction.

摘要

本研究提出了一种新的实验方法，旨在研究沥青质与固体表面的分子相互作用，以及这些相互作用如何影响润湿性的变化。通过改变方解石表面的润湿性（通过接触角测量进行评估）来评估该方法的影响。此外，使用场发射扫描电子显微镜、元素分析、傅里叶变换红外光谱和zeta电位测量等技术分析了沥青质馏分的性质。对四个不同的伊朗油样（命名为A、B、F和G）进行了实验。结果表明，与其他样品相比，B样品显著提高了表面的亲油性能。基于分馏研究，将全沥青质分离为四个亚馏分，称为[公式：见正文]、[公式：见正文]、[公式：见正文]和[公式：见正文]。用甲苯洗涤后，B样品中24.16%的沥青质仍附着在方解石表面。润湿性与附着在表面的沥青质的极性有关，而不是与全沥青质的极性有关。这表明受沥青质影响的表面性质不仅归因于它们固有的极性，还归因于它们与表面的相互作用。此外，润湿性和zeta电位之间似乎存在相关性，这与[公式：见正文]馏分有关。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/99131aa696b0/41598_2025_12599_Fig18_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/f9cfde338cf0/41598_2025_12599_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/fd62c21a2da4/41598_2025_12599_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/27fa53167272/41598_2025_12599_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/ae976c988416/41598_2025_12599_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/e6d1ff8a1dcb/41598_2025_12599_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/573e1eb2a764/41598_2025_12599_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/59b79dfc875f/41598_2025_12599_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/7d6dfece153c/41598_2025_12599_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/351aaad088dd/41598_2025_12599_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/70bd0699e106/41598_2025_12599_Fig10_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/d546a931fafc/41598_2025_12599_Fig11_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/e9745a36acbb/41598_2025_12599_Fig12_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/0a1b98d7f9b8/41598_2025_12599_Fig13_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/ff1d4058c67c/41598_2025_12599_Fig14_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/2ad2ae174a0a/41598_2025_12599_Fig15_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/e8fa7e8e9bd7/41598_2025_12599_Fig16_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/3a231cbe8146/41598_2025_12599_Fig17_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/99131aa696b0/41598_2025_12599_Fig18_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/f9cfde338cf0/41598_2025_12599_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/fd62c21a2da4/41598_2025_12599_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/27fa53167272/41598_2025_12599_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/ae976c988416/41598_2025_12599_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/e6d1ff8a1dcb/41598_2025_12599_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/573e1eb2a764/41598_2025_12599_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/59b79dfc875f/41598_2025_12599_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/7d6dfece153c/41598_2025_12599_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/351aaad088dd/41598_2025_12599_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/70bd0699e106/41598_2025_12599_Fig10_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/d546a931fafc/41598_2025_12599_Fig11_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/e9745a36acbb/41598_2025_12599_Fig12_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/0a1b98d7f9b8/41598_2025_12599_Fig13_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/ff1d4058c67c/41598_2025_12599_Fig14_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/2ad2ae174a0a/41598_2025_12599_Fig15_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/e8fa7e8e9bd7/41598_2025_12599_Fig16_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/3a231cbe8146/41598_2025_12599_Fig17_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5f3/12322175/99131aa696b0/41598_2025_12599_Fig18_HTML.jpg

相似文献

1
Molecular level characterization of interactions between asphaltene and solid surface for forecasting changes in wettability.用于预测润湿性变化的沥青质与固体表面相互作用的分子水平表征
Sci Rep. 2025 Aug 4;15(1):28394. doi: 10.1038/s41598-025-12599-y.
2
A Novel Design of a Portable Birdcage via Meander Line Antenna (MLA) to Lower Beta Amyloid (Aβ) in Alzheimer's Disease.一种通过曲折线天线（MLA）设计的便携式鸟笼，用于降低阿尔茨海默病中的β淀粉样蛋白（Aβ）。
IEEE J Transl Eng Health Med. 2025 Apr 10;13:158-173. doi: 10.1109/JTEHM.2025.3559693. eCollection 2025.
3
Management of urinary stones by experts in stone disease (ESD 2025).结石病专家对尿路结石的管理（2025年结石病专家共识）
Arch Ital Urol Androl. 2025 Jun 30;97(2):14085. doi: 10.4081/aiua.2025.14085.
4
Comprehensive experimental study of multivariable oil-brine-rock interactions: impact of brine-rock chemistry and crude oil polarity on enhanced oil recovery in carbonate reservoirs.多变量油-盐水-岩石相互作用的综合实验研究：盐水-岩石化学和原油极性对碳酸盐岩油藏提高采收率的影响
Sci Rep. 2025 Jul 15;15(1):25605. doi: 10.1038/s41598-025-09448-3.
5
Health professionals' experience of teamwork education in acute hospital settings: a systematic review of qualitative literature.医疗专业人员在急症医院环境中团队合作教育的经验：对定性文献的系统综述
JBI Database System Rev Implement Rep. 2016 Apr;14(4):96-137. doi: 10.11124/JBISRIR-2016-1843.
6
Variation within and between digital pathology and light microscopy for the diagnosis of histopathology slides: blinded crossover comparison study.数字病理学与光学显微镜检查在组织病理学切片诊断中的内部及相互间差异：双盲交叉对比研究
Health Technol Assess. 2025 Jul;29(30):1-75. doi: 10.3310/SPLK4325.
7
Short-Term Memory Impairment短期记忆障碍
8
Systemic treatments for metastatic cutaneous melanoma.转移性皮肤黑色素瘤的全身治疗
Cochrane Database Syst Rev. 2018 Feb 6;2(2):CD011123. doi: 10.1002/14651858.CD011123.pub2.
9
Optimized biosynthesis and performance enhancement of γ-PGA from Bacillus licheniformis: a study on wettability, microstructure, and environmental performance.地衣芽孢杆菌γ-聚谷氨酸的优化生物合成及性能增强：关于润湿性、微观结构和环境性能的研究
Sci Rep. 2025 Jul 7;15(1):24252. doi: 10.1038/s41598-025-99084-8.
10
The risks, benefits, and resource implications of different diets in gastrostomy-fed children: The YourTube mixed method study.胃造口喂养儿童不同饮食的风险、益处及资源影响：YouTube混合方法研究
Health Technol Assess. 2025 Jul;29(25):1-21. doi: 10.3310/RRREF7741.

本文引用的文献

1
Asphaltene deposition effects on reservoir rock wettability and modification strategies.沥青质沉积对储层岩石润湿性的影响及改性策略。
Heliyon. 2024 Sep 24;10(21):e38436. doi: 10.1016/j.heliyon.2024.e38436. eCollection 2024 Nov 15.
2
Mechanistic understanding of asphaltene precipitation and oil recovery enhancement using SiO and CaCO nano-inhibitors.使用SiO和CaCO纳米抑制剂对沥青质沉淀和原油采收率提高的机理理解。
Sci Rep. 2024 Jul 2;14(1):15249. doi: 10.1038/s41598-024-65995-1.
3
Research Progress in Nanoparticle Inhibitors for Crude Oil Asphaltene Deposition.
用于原油沥青质沉积的纳米颗粒抑制剂的研究进展
Molecules. 2024 Mar 3;29(5):1135. doi: 10.3390/molecules29051135.
4
Effectiveness of inhibitors to prevent asphaltene aggregation: Insights from atomistic and molecular simulations.抑制剂防止沥青质聚集的有效性：来自原子和分子模拟的见解
J Chem Phys. 2024 Mar 7;160(9). doi: 10.1063/5.0190779.
5
Impact of Asphaltene Precipitation and Deposition on Wettability and Permeability.沥青质沉淀与沉积对润湿性和渗透率的影响
ACS Omega. 2021 Jul 26;6(31):20091-20102. doi: 10.1021/acsomega.1c03198. eCollection 2021 Aug 10.
6
A review of wettability alteration using surfactants in carbonate reservoirs.碳酸盐岩油藏中使用表面活性剂进行润湿性改变的综述。
Adv Colloid Interface Sci. 2021 Aug;294:102477. doi: 10.1016/j.cis.2021.102477. Epub 2021 Jun 29.
7
Toward molecular characterization of asphaltene from different origins under different conditions by means of FT-IR spectroscopy.通过傅里叶变换红外光谱法对不同来源、不同条件下的沥青质进行分子表征。
Adv Colloid Interface Sci. 2021 Mar;289:102314. doi: 10.1016/j.cis.2020.102314. Epub 2020 Dec 17.
8
Zeta potential of artificial and natural calcite in aqueous solution.水溶液中人工合成和天然方解石的 Zeta 电位。
Adv Colloid Interface Sci. 2017 Feb;240:60-76. doi: 10.1016/j.cis.2016.12.006. Epub 2016 Dec 26.
9
The kinetics and mechanisms of amorphous calcium carbonate (ACC) crystallization to calcite, via vaterite.无定形碳酸钙（ACC）经水碳酸钙（vaterite）向方解石结晶的动力学和机制。
Nanoscale. 2011 Jan;3(1):265-71. doi: 10.1039/c0nr00589d. Epub 2010 Nov 10.
10
Zeta potential measurement of calcium carbonate.
J Colloid Interface Sci. 2003 May 1;261(1):115-26. doi: 10.1016/s0021-9797(03)00057-2.