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在聚偏氟乙烯基体中用多壁碳纳米管和石墨增强的碳基聚合物复合材料的合成与表征。

Synthesis and characterization of carbon based polymer composites reinforced with MWCNTs and graphite in PVDF matrix.

作者信息

Laad Meena, Sur Anirban, Kale Girish, Razoumny Yury, Shalu Akhila

机构信息

Symbiosis Institute of Technology (SIT), Symbiosis International (Deemed University) (SIU), Pune, Maharashtra, India.

School of Chemical and Process Engineering, University of Leeds, Leeds, UK.

出版信息

Sci Rep. 2025 Aug 7;15(1):28928. doi: 10.1038/s41598-025-13421-5.

Abstract

Lightweight polymer composites have drawn a lot of interest because of their improved mechanical, electrical, and thermal properties, which make them perfect for cutting-edge engineering applications. This work reports the synthesis of hybrid polymer composites by integrating multi-walled carbon nanotubes (MWCNTs) into a polyvinylidene fluoride (PVDF) matrix. The synergistic effect of MWCNTs and graphite nanoparticles was explored to achieve improved structural and functional performance. The composites were synthesised using a solution casting method to ensure dispersion of the fillers within the polymer matrix. The fabricated composite was characterized using XRD, FTIR, EDS and FESEM to evaluate its structural, compositional, morphological and elemental properties. XRD confirmed the nanofillers' crystalline phases and structural integrity within the polymer matrix. FTIR spectroscopy identified the characteristic functional groups, verifying interactions between PVDF and the incorporated nanofillers. FESEM images revealed a fibrous CNT network blended within the PVDF polymer matrix and distinct graphite flakes, ensuring uniform dispersion and adhesion. EDS confirmed the elemental composition, highlighting the presence of carbon and fluorine as primary constituents. These combined techniques provide comprehensive insight into the composite's composition, structure and potential functional properties for advanced applications.

摘要

轻质聚合物复合材料因其改进的机械、电气和热性能而备受关注,这使其非常适合前沿工程应用。这项工作报道了通过将多壁碳纳米管(MWCNTs)集成到聚偏氟乙烯(PVDF)基体中来合成杂化聚合物复合材料。探索了MWCNTs与石墨纳米颗粒的协同效应,以实现结构和功能性能的改进。使用溶液浇铸法合成复合材料,以确保填料在聚合物基体中的分散。使用XRD、FTIR、EDS和FESEM对制备的复合材料进行表征,以评估其结构、组成、形态和元素性质。XRD证实了纳米填料在聚合物基体中的晶相和结构完整性。FTIR光谱确定了特征官能团,验证了PVDF与掺入的纳米填料之间的相互作用。FESEM图像显示在PVDF聚合物基体中混合有纤维状的CNT网络和明显的石墨薄片,确保了均匀分散和粘附。EDS证实了元素组成,突出了碳和氟作为主要成分的存在。这些综合技术为复合材料的组成、结构以及先进应用的潜在功能特性提供了全面的见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/acd5/12331976/48380032b125/41598_2025_13421_Fig1_HTML.jpg

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