4,4'-联吡啶-1,1'-二鎓四氯化二氟锡（IV）一水合物
4,4'-Bi-pyridine-1,1'-diium tetra-chloridodi-fluorido-stannate(IV) monohydrate.
作者信息
Kemmouche Amina, Ghallab Rochdi, Merazig Hocine
机构信息
Ecole Nationale Superieure de Biotechnologie de Constantine, Algeria.
Laboratoire de Technologie des Materiaux Avances Ecole Nationale Polytechnique de Constantine Algeria.
出版信息
IUCrdata. 2025 Jul 11;10(Pt 7):x250596. doi: 10.1107/S2414314625005966. eCollection 2025 Jul.
In the title hydrated salt, (CHN)[SnFCl]·HO, the dihedral angle between the pyridinium rings in the cation is 40.5 (4)° and the F atoms in the octa-hedral complex anion have a disposition [F-Sn-F = 85.32 (17)°]. In the extended structure, alternating cationic and anionic layers occur, linked by extensive hydrogen bonding, with water mol-ecules inserted between the layers.
在标题水合盐(CHN)[SnFCl]·HO中，阳离子中吡啶环之间的二面角为40.5 (4)°，八面体络合阴离子中的F原子具有[F-Sn-F = 85.32 (17)°]的排列方式。在扩展结构中，通过广泛的氢键连接形成交替的阳离子层和阴离子层，水分子插入层间。
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