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用于高效油水分离的超疏水磁性纳米材料的设计与应用:综述

Design and Application of Superhydrophobic Magnetic Nanomaterials for Efficient Oil-Water Separation: A Critical Review.

作者信息

Kudaibergenova Rabiga M, Baibazarova Elvira A, Balpanova Didara T, Sugurbekova Gulnar K, Serikbayeva Aizhan M, Kalmakhanova Marzhan S, Murzakasymova Nazgul S, Kabdushev Arman A, Orynbayev Seitzhan A

机构信息

Department of Chemistry and Chemical Technology, Faculty of Technology, M. Kh. Dulaty Taraz University, Taraz 080000, Kazakhstan.

Department of Chemistry, School of Pharmacy, Kazakh National Medical University Named After S.D. Asfendiyarov, Almaty 050000, Kazakhstan.

出版信息

Molecules. 2025 Aug 7;30(15):3313. doi: 10.3390/molecules30153313.


DOI:10.3390/molecules30153313
PMID:40807488
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12348836/
Abstract

Superhydrophobic magnetic nanomaterials (SHMNMs) are emerging as multifunctional platforms for efficient oil-water separation due to their combination of extreme water repellency, strong oil affinity, and external magnetic responsiveness. This review presents a comprehensive analysis of recent advances in the design, synthesis, and environmental application of SHMNMs. The theoretical foundations of superhydrophobicity and the physicochemical behavior of magnetic nanoparticles are first outlined, followed by discussion of their synergistic integration. Key fabrication techniques-such as sol-gel synthesis, electrospinning, dip-coating, laser-assisted processing, and the use of biomass-derived precursors-are critically assessed in terms of their ability to tailor surface morphology, chemical functionality, and long-term durability. The review further explores the mechanisms of oil adsorption, magnetic separation, and material reusability under realistic environmental conditions. Special attention is paid to the scalability, mechanical resilience, and environmental compatibility of SHMNMs in the context of water treatment technologies. Current limitations, including reduced efficiency in harsh media, potential environmental risks, and challenges in material regeneration, are discussed. This work provides a structured overview that could support the rational development of next-generation superhydrophobic materials tailored for sustainable and high-performance separation of oil and organic pollutants from water.

摘要

超疏水磁性纳米材料(SHMNMs)因其兼具极强的疏水性、对油的强亲和力和外部磁响应性,正成为用于高效油水分离的多功能平台。本文综述对SHMNMs在设计、合成及环境应用方面的最新进展进行了全面分析。首先概述了超疏水性的理论基础和磁性纳米颗粒的物理化学行为,接着讨论了它们的协同整合。对关键制备技术,如溶胶 - 凝胶合成、静电纺丝、浸涂、激光辅助加工以及使用生物质衍生前驱体等,根据其调整表面形态、化学功能和长期耐久性的能力进行了批判性评估。综述进一步探讨了在实际环境条件下油吸附、磁分离和材料可重复使用性的机制。在水处理技术背景下,特别关注了SHMNMs的可扩展性、机械弹性和环境兼容性。讨论了当前的局限性,包括在苛刻介质中效率降低、潜在的环境风险以及材料再生方面的挑战。这项工作提供了一个结构化的概述,可为合理开发下一代超疏水材料提供支持,这些材料旨在从水中可持续且高效地分离油和有机污染物。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45aa/12348836/39dfd01c1673/molecules-30-03313-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45aa/12348836/bc544741cc74/molecules-30-03313-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45aa/12348836/39dfd01c1673/molecules-30-03313-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45aa/12348836/bc544741cc74/molecules-30-03313-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45aa/12348836/39dfd01c1673/molecules-30-03313-g002.jpg

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本文引用的文献

[1]
Solvent-regulable interfacial groups enable on-demand superhydrophobic/superhydrophilic silica aerogels.

Nat Commun. 2025-3-5

[2]
Superhydrophobic magnetic melamine sponge modified by flowerlike ZnO and stearic acid using dip coating method for oil and water separation.

Sci Rep. 2025-3-3

[3]
Carbon-Nanotube-Based Superhydrophobic Magnetic Nanomaterial as Absorbent for Rapid and Efficient Oil/Water Separation.

Nanomaterials (Basel). 2024-12-3

[4]
Cyrene-Enabled Green Electrospinning of Nanofibrous Graphene-Based Membranes for Water Desalination via Membrane Distillation.

ACS Sustain Chem Eng. 2024-11-25

[5]
A review on recent progress and techniques used for fabricating superhydrophobic coatings derived from biobased materials.

RSC Adv. 2024-10-17

[6]
Durably Superhydrophobic Magnetic Cobalt Ferrites for Highly Efficient Oil-Water Separation and Fast Microplastic Removal.

Langmuir. 2024-10-15

[7]
Bioinspired superwetting oil-water separation strategy: toward the era of openness.

Chem Soc Rev. 2024-10-14

[8]
Micropatterned superhydrophobic meshes coated with low-cost carbon nanoparticles for efficient oil/water separation.

RSC Adv. 2024-6-27

[9]
A facile approach for oil-water separation using superhydrophobic polystyrene-silica coated stainless steel mesh bucket.

Mar Pollut Bull. 2024-1

[10]
Preparation of the graphene-based smart hydrophobic nanocomposite and its application in oil/water separation.

Sci Rep. 2023-11-13

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