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生物基阻燃剂在用于复合材料开发的可持续环氧树脂体系中的作用。

Effect of Bio-Based Flame Retardants in Sustainable Epoxy Systems for the Development of Composite Materials.

作者信息

Ares-Elejoste Patricia, Seoane-Rivero Rubén, Gandarias Inaki, Ballestero Jesus, Alonso-Amondarain Ane Libe

机构信息

GAIKER Technology Centre, Basque Research and Technology Alliance (BRTA), Parque Tecnológico de Bizkaia, Edificio 202, 48170 Zamudio, Spain.

Chemical and Environmental Engineering Department, University of the Basque Country (UPV/EHU), Alameda Urquijo s/n, 48013 Bilbao, Spain.

出版信息

Polymers (Basel). 2025 Jul 22;17(15):2001. doi: 10.3390/polym17152001.

DOI:10.3390/polym17152001
PMID:40808049
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12349320/
Abstract

The composite materials industry is increasingly seeking sustainable alternatives to mitigate the environmental impact of end-of-life materials. As a result, many sectors are transitioning toward bio-based or partially bio-based matrices (e.g., epoxy resins) to preserve material properties while improving sustainability. The transportation sector, in particular, demands materials that meet stringent mechanical and fire resistance standards. In this study, various epoxy systems with bio-based and/or recyclable content were investigated, along with renewable additives designed to enhance fire resistance through their functional groups and chemical structure. The research focused on developing formulations compatible with Sheet Moulding Compound (SMC) technology, which is widely used in transportation applications. Through extensive testing, materials with high bio-based content were successfully developed, exhibiting competitive mechanical properties and compliance with key fire safety requirements of the railway sector, as per the EN 45545-2 standard.

摘要

复合材料行业越来越多地寻求可持续替代方案,以减轻报废材料对环境的影响。因此,许多行业正在转向生物基或部分生物基基体(如环氧树脂),以在提高可持续性的同时保持材料性能。特别是运输部门,需要符合严格机械和防火标准的材料。在本研究中,对具有生物基和/或可回收成分的各种环氧体系以及旨在通过其官能团和化学结构提高防火性能的可再生添加剂进行了研究。该研究重点是开发与广泛应用于运输领域的片状模塑料(SMC)技术兼容的配方。通过大量测试,成功开发出了具有高生物基含量的材料,这些材料具有具有竞争力的机械性能,并符合EN 45545-2标准规定的铁路部门关键消防安全要求。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/12349320/c157a5e57b01/polymers-17-02001-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/12349320/2bbfb6627cdc/polymers-17-02001-g001.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/12349320/436d1d84dd2d/polymers-17-02001-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/12349320/413a4344f2d3/polymers-17-02001-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/12349320/80973a615d91/polymers-17-02001-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/12349320/b95c7f1e7dd7/polymers-17-02001-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/12349320/c157a5e57b01/polymers-17-02001-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/12349320/2bbfb6627cdc/polymers-17-02001-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/12349320/5f8cf53dbbdf/polymers-17-02001-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/12349320/5410e90bdef6/polymers-17-02001-g003a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/12349320/436d1d84dd2d/polymers-17-02001-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/12349320/413a4344f2d3/polymers-17-02001-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/12349320/80973a615d91/polymers-17-02001-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/12349320/b95c7f1e7dd7/polymers-17-02001-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/12349320/c157a5e57b01/polymers-17-02001-g008.jpg

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本文引用的文献

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Int J Biol Macromol. 2024 Nov;279(Pt 1):135001. doi: 10.1016/j.ijbiomac.2024.135001. Epub 2024 Aug 23.
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Species-specific and habitat-dependent bioaccumulation of halogenated flame retardants in marine organisms from estuary to coastal seas.河口至沿海海域海洋生物中卤代阻燃剂的物种特异性和生境依赖性生物累积。
J Hazard Mater. 2024 Jul 5;472:134529. doi: 10.1016/j.jhazmat.2024.134529. Epub 2024 May 7.
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Int J Biol Macromol. 2024 Apr;264(Pt 2):130518. doi: 10.1016/j.ijbiomac.2024.130518. Epub 2024 Feb 28.
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Sustainable Alternatives for the Development of Thermoset Composites with Low Environmental Impact.对环境影响较小的热固性复合材料开发的可持续替代方案。
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