Jin Yi, Chen Shen, Xie Jinlan, Xu Weixing, Zeng Yunhang, Shi Bi
College of Biomass Science and Engineering, Sichuan University, Chengdu 610065, China.
National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, China.
Polymers (Basel). 2025 Jul 26;17(15):2043. doi: 10.3390/polym17152043.
Lightweightness and durability are key consumer demands for footwear. To address the issues of deformation and poor durability in foamed sole materials, this study integrates natural fibers into the formulation of foamed rubber. The effects of natural fiber incorporation on density, mechanical properties, creep behavior, anti-slip performance, and aging resistance were comprehensively analyzed. Additionally, the study explored the mechanisms underlying the improved performance of the modified rubber materials. The results revealed that natural fiber integration significantly enhanced the structural stability, strength, and aging resistance of natural rubber (NR). Among the fibers compared, collagen fibers (CF) proved to be the most effective modifier for foamed NR. The density, tensile strength, tear strength, and coefficient of friction of CF-modified foamed NR (CF-NR) were found to be 0.72 g/cm, 10.1 MPa, 48.0 N/mm, and 1.105, respectively, meeting the standard requirements for sole materials. Furthermore, CF-NR demonstrated a recoverable deformation of 4.58% and a negligible irreversible deformation of 0.10%, indicating a successful balance between comfort and durability. This performance enhancement can be attributed to the supportive role of CF in the pore structure, along with its inherent flexibility and recoverability. This work presents a novel approach for the development of high-quality, lightweight footwear in the sole material industry.
轻便性和耐用性是消费者对鞋类的关键需求。为了解决泡沫鞋底材料的变形和耐久性差的问题,本研究将天然纤维融入泡沫橡胶配方中。全面分析了天然纤维掺入对密度、力学性能、蠕变行为、防滑性能和抗老化性能的影响。此外,该研究还探讨了改性橡胶材料性能改善的潜在机制。结果表明,天然纤维的加入显著提高了天然橡胶(NR)的结构稳定性、强度和抗老化性能。在比较的纤维中,胶原纤维(CF)被证明是泡沫NR最有效的改性剂。发现CF改性泡沫NR(CF-NR)的密度、拉伸强度、撕裂强度和摩擦系数分别为0.72 g/cm、10.1 MPa、48.0 N/mm和1.105,符合鞋底材料的标准要求。此外,CF-NR的可恢复变形为4.58%,不可逆变形可忽略不计,为0.10%,表明在舒适性和耐用性之间取得了成功的平衡。这种性能的提高可归因于CF在孔隙结构中的支撑作用,以及其固有的柔韧性和可恢复性。这项工作为鞋底材料行业开发高质量、轻便的鞋类提供了一种新方法。