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金属卤化物钙钛矿的无溶剂制备方法

Solvent-Free Fabrication Methods of Metal Halide Perovskites.

作者信息

Ji Ran, Mallick Arindam, Rivkin Boris, Yuce-Cakir Hurriyet, Jurchescu Oana D, Vaynzof Yana

机构信息

Chair for Emerging Electronic Technologies, Technical University of Dresden, Nöthnitzer Str. 61, 01187, Dresden, Germany.

Leibniz-Institute for Solid State and Materials Research Dresden, Helmholtzstraße 20, 01069, Dresden, Germany.

出版信息

Adv Mater. 2025 Oct;37(40):e2416604. doi: 10.1002/adma.202416604. Epub 2025 Aug 21.

DOI:10.1002/adma.202416604
PMID:40838460
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12510301/
Abstract

Metal halide perovskites have ascended as a remarkable class of materials in recent years, demonstrating exceptional promise for application in various electronic and optoelectronic devices. The vast majority of research on these materials focuses on their processing from solution, which is relatively easily executed in laboratory settings, but its scalability for industrial mass production remains a significant hurdle. Furthermore, its reliance on highly toxic solvents imposes limitations with respect to large-area fabrication and have a negative environmental impact. This review comprehensively explores the current status of solvent-free fabrication methods for metal halide perovskites, outlines the current challenges and opportunities, and provides a critical assessment of the technological readiness and future research directions. The development of robust and scalable solvent-free fabrication methodologies is essential to realizing the full potential of metal halide perovskites. We hope that this review will serve as a catalyst, inspiring and guiding researchers to explore new strategies for the solvent-free deposition of these remarkable materials, thereby expediting their integration into technological applications.

摘要

近年来，金属卤化物钙钛矿已成为一类引人注目的材料，在各种电子和光电器件中的应用显示出巨大潜力。对这些材料的绝大多数研究都集中在它们的溶液加工上，这在实验室环境中相对容易实现，但其用于工业大规模生产的可扩展性仍然是一个重大障碍。此外，其对剧毒溶剂的依赖在大面积制造方面存在局限性，并对环境有负面影响。本综述全面探讨了金属卤化物钙钛矿无溶剂制造方法的现状，概述了当前的挑战和机遇，并对技术成熟度和未来研究方向进行了批判性评估。开发强大且可扩展的无溶剂制造方法对于实现金属卤化物钙钛矿的全部潜力至关重要。我们希望本综述能起到催化剂的作用，激励和引导研究人员探索这些卓越材料无溶剂沉积的新策略，从而加速它们融入技术应用。

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