联吡啶中的旋转运动：构象研究。
Rotational Motion in Bispidines: A Conformational Study.
作者信息
Migliano Francesco, Pozzi Luca, Citarella Andrea, Macetti Giovanni, Lo Presti Leonardo, Passarella Daniele, Fasano Valerio
机构信息
Department of Chemistry, Università degli Studi di Milano, Via Golgi 19, 20133 Milano, Italy.
出版信息
Org Lett. 2025 Sep 5;27(35):9669-9673. doi: 10.1021/acs.orglett.5c02839. Epub 2025 Aug 26.
A detailed conformational analysis of -substituted bispidines has been performed to determine the factors governing the restricted rotational motion induced by the substituents. This investigation combines computational studies of the transition state involved in the rotation with experimental characterization of the rotamers arising from the restricted rotation.
已对β-取代的双吡啶进行了详细的构象分析，以确定影响取代基诱导的受限旋转运动的因素。这项研究将旋转过程中涉及的过渡态的计算研究与受限旋转产生的旋转异构体的实验表征相结合。
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