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适用于裂缝性地层油气钻井的高强度强触变性凝胶。

High Strength and Strong Thixotropic Gel Suitable for Oil and Gas Drilling in Fractured Formation.

作者信息

Yan Yancheng, Tang Tao, Ou Biao, Wu Jianzhong, Liu Yuan, Yang Jingbin

机构信息

Sinopec Southwest Oil & Gas Company Engineering Technology Research Institute, Chengdu 610031, China.

School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China.

出版信息

Gels. 2025 Jul 26;11(8):578. doi: 10.3390/gels11080578.

Abstract

In petroleum exploration and production, lost circulation not only significantly increases exploration and development costs and operational cycles but may also lead to major incidents such as wellbore instability or even project abandonment. This paper constructs a polymer gel plugging system by optimizing high-molecular-weight polymers, crosslinker systems, and resin hardeners. The optimized system composition was determined as 1% polymer J-1, 0.3% catechol, 0.6% hexamethylenetetramine (HMTA), and 15% urea-formaldehyde resin. Experimental studies demonstrated that during the initial stage (0-3 days) at 120 °C, the optimized gel system maintained a storage modulus (G') of 17.5 Pa and a loss modulus (G″) of 4.3 Pa. When the aging period was extended to 9 days, G' and G″ decreased to 16 Pa and 4 Pa, respectively. The insignificant reduction in gel strength indicates excellent thermal stability of the gel system. The gel exhibited superior self-filling capacity during migration, enabling complete filling of fractures of varying sizes. After aging for 1 day at 120 °C, the plugging capacity of the gel system under water flooding and gas flooding conditions was 166 kPa/m and 122 kPa/m, respectively. Furthermore, a complete gel barrier layer formed within a 6 mm wide vertical fracture, demonstrating a pressure-bearing capacity of 105.6 kPa. This system shows good effectiveness for wellbore isolation and fracture plugging. The polymer gel plugging system studied in this paper can simplify lost circulation treatment procedures while enhancing plugging strength, providing theoretical support and technical solutions for addressing lost circulation challenges.

摘要

在石油勘探与生产中,漏失不仅会显著增加勘探开发成本和作业周期,还可能导致诸如井筒不稳定甚至项目废弃等重大事故。本文通过优化高分子聚合物、交联剂体系和树脂固化剂构建了一种聚合物凝胶堵漏体系。优化后的体系组成确定为1%的聚合物J - 1、0.3%的邻苯二酚、0.6%的六亚甲基四胺(HMTA)和15%的脲醛树脂。实验研究表明,在120℃的初始阶段(0 - 3天),优化后的凝胶体系储能模量(G')为17.5 Pa,损耗模量(G″)为4.3 Pa。当老化时间延长至9天时,G'和G″分别降至16 Pa和4 Pa。凝胶强度的微小降低表明该凝胶体系具有优异的热稳定性。该凝胶在运移过程中表现出卓越的自充填能力,能够完全充填不同尺寸的裂缝。在120℃老化1天后,该凝胶体系在水驱和气驱条件下的堵漏能力分别为166 kPa/m和122 kPa/m。此外,在6 mm宽的垂直裂缝内形成了完整的凝胶阻挡层,承压能力为105.6 kPa。该体系在井筒隔离和裂缝堵漏方面显示出良好的效果。本文研究的聚合物凝胶堵漏体系能够简化漏失处理程序,同时提高堵漏强度,为应对漏失挑战提供理论支持和技术解决方案。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb88/12386153/d2730dfdcb41/gels-11-00578-g001.jpg

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