用于潜在检测和修复化学、生物、放射性和核污染的硫代磷酰化-PMMH树枝状大分子：精选研究及一般指南与程序

Thiophosphoryl-PMMH Dendrimers for Potential Detection and Remediation of CBRN Contamination: Selected Studies and General Guidelines and Procedures.

作者信息

Lalik Sebastian, Gonciarz Agnieszka, Pich Robert, Bogdanowicz Krzysztof A, Pellowski Witalis, Miedziak Jacek, Szczepaniak Marcin, Marzec Monika, Iwan Agnieszka

机构信息

Institute of Physics, Jagiellonian University, Łojasiewicza 11, 30-348 Krakow, Poland.

Faculty of Security and Safety Research, General Tadeusz Kosciuszko Military University of Land Forces, Czajkowskiego 109, 51-147 Wrocław, Poland.

出版信息

Materials (Basel). 2025 Aug 13;18(16):3805. doi: 10.3390/ma18163805.

DOI:10.3390/ma18163805

PMID:40870123

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12387595/

Abstract

The main idea of this work is to implement organic nanomaterials, such as thiophosphoryl-PMMH dendrimers, for the potential detection and remediation of chemical, biological, radiological, and nuclear (CBRN) contamination. An IR-thermal technique for determining the material specific surface morphology and defects of a thiophosphoryl-PMMH dendrimers is presented. Optical (UV-Vis), thermal (DSC), and electrical (dielectric spectroscopy and thermal imaging) characterizations show that the generation and number of surface groups influence the properties of the investigated dendrimers. Finally, general guidelines and procedures of thiophosphoryl-PMMH dendrimers with various generations are proposed for both civilian and military users.

摘要

这项工作的主要思路是采用有机纳米材料，如硫代磷酰基 - PMMH树枝状大分子，用于潜在检测和修复化学、生物、放射性及核（CBRN）污染。本文介绍了一种用于确定硫代磷酰基 - PMMH树枝状大分子材料特定表面形态和缺陷的红外热技术。光学（紫外 - 可见）、热学（差示扫描量热法）和电学（介电谱和热成像）表征表明，表面基团的代数和数量会影响所研究树枝状大分子的性能。最后，针对民用和军事用户，提出了不同代数硫代磷酰基 - PMMH树枝状大分子的一般指导方针和程序。