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通过低温织构工程提高基于KNN的无铅压电多层致动器的应变性能

Enhanced Strain Properties in KNN-Based Lead-free Piezoelectric Multilayer Actuators by Low-Temperature Texture Engineering.

作者信息

Nie Jingkai, Qiu Ning, Zhang Shicheng, He Qiang, Chen Xiaogang, Han Yu, Tian Yi, Tian Chen

机构信息

China Electric Power Research Institute, Beijing 100192, China.

State Key Laboratory of Advanced Power Transmission Technology, Beijing 102209, China.

出版信息

ACS Omega. 2025 Aug 22;10(34):38995-39001. doi: 10.1021/acsomega.5c05074. eCollection 2025 Sep 2.

DOI:10.1021/acsomega.5c05074
PMID:40918338
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12409562/
Abstract

In response to the demand for lead-free replacement of multilayer piezoelectric actuators (MLAs), KNN-based lead-free piezoceramics with high curie temperatures and environmental friendliness are selected for the application study. To improve the piezoelectric properties of piezoelectric ceramics, a texture approach was adopted, and 0.2% CuO was added as a sintering aid; the TGG texturing technique was combined with the stacked element cofiring technique. Finally, we investigate the relevant properties of KNN-based multilayer piezoelectric actuators. Here, a compositional system of 0.96-(NaK)-(NbSb)-O-0.01CaZrO-0.03-(KBiHfO) (KNNS-KBH-CZ) was chosen to fabricate multilayer piezoelectric actuators. The texturing degree of KNNS-KBH-CZ/CuO reaches as high as 75%, leading to a high strain performance (strain of 0.14%, * of 466 pm/V) under a low electric field (3 kV/mm), highlighting the potential application of KNN-based piezoelectric ceramics in the field of piezoelectric actuators.

摘要

为响应多层压电致动器(MLA)无铅替代的需求,选择了具有高居里温度和环境友好性的基于KNN的无铅压电陶瓷进行应用研究。为了改善压电陶瓷的压电性能,采用了织构化方法,并添加了0.2%的CuO作为烧结助剂;将TGG织构化技术与叠层元件共烧技术相结合。最后,研究了基于KNN的多层压电致动器的相关性能。在此,选择了0.96-(NaK)-(NbSb)-O-0.01CaZrO-0.03-(KBiHfO)(KNNS-KBH-CZ)的成分体系来制造多层压电致动器。KNNS-KBH-CZ/CuO的织构化程度高达75%,在低电场(3 kV/mm)下具有高应变性能(应变0.14%,d*为466 pm/V),突出了基于KNN的压电陶瓷在压电致动器领域的潜在应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1587/12409562/b70fc3cf4c11/ao5c05074_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1587/12409562/38773b10f74b/ao5c05074_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1587/12409562/9b95e1b3338d/ao5c05074_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1587/12409562/97c00bdf18df/ao5c05074_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1587/12409562/eecc9b7211c5/ao5c05074_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1587/12409562/0f55bb20a1f0/ao5c05074_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1587/12409562/dc81e5478448/ao5c05074_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1587/12409562/b70fc3cf4c11/ao5c05074_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1587/12409562/38773b10f74b/ao5c05074_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1587/12409562/9b95e1b3338d/ao5c05074_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1587/12409562/97c00bdf18df/ao5c05074_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1587/12409562/eecc9b7211c5/ao5c05074_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1587/12409562/0f55bb20a1f0/ao5c05074_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1587/12409562/dc81e5478448/ao5c05074_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1587/12409562/b70fc3cf4c11/ao5c05074_0007.jpg

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本文引用的文献

1
Ultrahigh thermal stability and piezoelectricity of lead-free KNN-based texture piezoceramics.无铅KNN基织构压电陶瓷的超高热稳定性和压电性
Nat Commun. 2024 Oct 18;15(1):9018. doi: 10.1038/s41467-024-53437-5.
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Innovation Strategy Selection Facilitates High-Performance Flexible Piezoelectric Sensors.创新策略选择助力高性能柔性压电传感器。
Sensors (Basel). 2020 May 15;20(10):2820. doi: 10.3390/s20102820.
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Lead-free piezoceramics.无铅压电陶瓷
Nature. 2004 Nov 4;432(7013):84-7. doi: 10.1038/nature03028. Epub 2004 Oct 31.