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电子辐照对氧化锌纳米线发光的增强与猝灭

Enhancement and quenching of ZnO nanowire luminescence by electron irradiation.

作者信息

Eobaldt Edwin, Zapf Maximilian, Wolf Gesine, Imani Sam, Nicklaus Johannes, Schönherr Sven, Ronning Carsten

机构信息

Institute of Solid State Physics, Friedrich Schiller University Jena, 07743, Jena, Germany.

出版信息

Discov Nano. 2025 Sep 12;20(1):159. doi: 10.1186/s11671-025-04352-1.

DOI:10.1186/s11671-025-04352-1
PMID:40938336
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12431989/
Abstract

Electron microscopy is an essential tool in the fabrication and characterization of optoelectronic devices. This study systematically investigated the stability of zinc oxide nanowires under electron irradiation, focusing on spontaneous and stimulated emission as well as their waveguiding properties. Spontaneous emission initially increases, which we attribute to the desorption of surface species, leading to a reduced surface band bending and enhanced luminescence. However, continued electron irradiation results in hydrocarbon formation on the nanowire surface, increasing waveguiding losses. These increased optical losses, in turn, raise the lasing threshold of nanowire lasers. Our findings offer valuable insights into the electron imaging parameters for optimizing semiconductor nanowires in optoelectronic applications.

摘要

电子显微镜是光电器件制造和表征中的重要工具。本研究系统地研究了氧化锌纳米线在电子辐照下的稳定性,重点关注自发发射和受激发射及其波导特性。自发发射最初会增加,我们将其归因于表面物种的解吸,这导致表面能带弯曲减小和发光增强。然而,持续的电子辐照会导致纳米线表面形成碳氢化合物,增加波导损耗。这些增加的光学损耗反过来又提高了纳米线激光器的激光阈值。我们的研究结果为优化光电子应用中的半导体纳米线的电子成像参数提供了有价值的见解。

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本文引用的文献

1
Electron Irradiation-Induced Degradation of TiN Thin Films on Quartz and Sapphire Substrates.电子辐照诱导石英和蓝宝石衬底上TiN薄膜的降解
ACS Omega. 2023 Dec 22;9(1):925-933. doi: 10.1021/acsomega.3c07053. eCollection 2024 Jan 9.
2
Volume electron microscopy.体积电子显微镜术
Nat Rev Methods Primers. 2022 Jul 7;2:51. doi: 10.1038/s43586-022-00131-9.
3
Spatially Resolved Dynamics of Cobalt Color Centers in ZnO Nanowires.氧化锌纳米线中钴色心的空间分辨动力学
Adv Sci (Weinh). 2022 Nov 20;10(1):e2205304. doi: 10.1002/advs.202205304.
4
Recent advances in nanorobotic manipulation inside scanning electron microscopes.扫描电子显微镜内纳米机器人操作的最新进展。
Microsyst Nanoeng. 2016 Jun 20;2:16024. doi: 10.1038/micronano.2016.24. eCollection 2016.
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Charge transfer-induced photoluminescence in ZnO nanoparticles.氧化锌纳米颗粒中电荷转移诱导的光致发光
Nanoscale. 2019 May 9;11(18):8736-8743. doi: 10.1039/c9nr02020a.
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Chip-scale high Q-factor glassblown microspherical shells for magnetic sensing.用于磁传感的芯片级高Q因子玻璃吹制微球壳
AIP Adv. 2018 Jun 14;8(6):065214. doi: 10.1063/1.5030460. eCollection 2018 Jun.
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Nano Lett. 2013 Mar 13;13(3):1080-5. doi: 10.1021/nl304362u. Epub 2013 Feb 15.
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Adv Mater. 2013 Feb 13;25(6):833-7, 832. doi: 10.1002/adma.201203692. Epub 2012 Nov 8.
10
High-order waveguide modes in ZnO nanowires.氧化锌纳米线中的高阶波导模式。
Nano Lett. 2007 Dec;7(12):3675-80. doi: 10.1021/nl071958w. Epub 2007 Nov 17.