Aradoaei Mihaela, Caramitu Alina Ruxandra, Lungu Magdalena Valentina, Ursan Andrei George, Ciobanu Romeo Cristian, Aflori Magdalena, Parfeni Adrian
Department of Electrical Measurements and Materials, Gheorghe Asachi Technical University, 700050 Iasi, Romania.
National Institute for Research and Development in Electrical Engineering ICPE-CA, Splaiul Unirii 313, 030138 Bucharest, Romania.
Polymers (Basel). 2025 Sep 2;17(17):2394. doi: 10.3390/polym17172394.
In this research, thermoplastic waste (polyethylene and propylene) from waste electrical and electronic equipment (WEEE) was used to manufacture polymer composite materials that included talc, fly ash, and elastomers, with tailored electromagnetic interference shielding properties, for the potential use for electric car components. A distribution of inorganic components within the polymer structures without particle clustering were observed, illustrating an effective melt compounding process. The gradual replacement of talc with fly ash lowered both the fluidity index and the softening temperature values. The increase in fly ash content resulted in higher values of both permittivity and dielectric loss factor. The novelty was related to a significant increase in both dielectric characteristics at increased quantities of fly ash at higher temperatures, an aspect more relevant at higher frequencies where they approached a steady value. The permittivity values surpassed five, and the dielectric loss factor values exceeded 0.04, fulfilling the requirements for their application in electrical equipment. The recipes containing 10% fly ash may guarantee an electromagnetic shielding effectiveness of at least 99% within the frequency domain of 0.1-4 GHz. Composites with greater amounts of fly ash can conduct heat more efficiently, leading to improved diffusivity and thermal conductivity values, with significant thermal conductivity values surpassing 0.2 W/(m*K). Finally, it was concluded that the composites with 10% talc, 10% fly ash, and elastomer using recycled high-density polyethylene might be the best choice for electric vehicle parts, in line with all required standards for these uses.
在本研究中,废弃电子电气设备(WEEE)中的热塑性废料(聚乙烯和聚丙烯)被用于制造聚合物复合材料,该复合材料包含滑石粉、粉煤灰和弹性体,具有定制的电磁干扰屏蔽性能,有望用于电动汽车部件。观察到聚合物结构内无颗粒团聚的无机成分分布,说明了有效的熔融共混过程。用粉煤灰逐渐替代滑石粉降低了流动指数和软化温度值。粉煤灰含量的增加导致介电常数和介电损耗因子值升高。新颖之处在于,在较高温度下粉煤灰含量增加时,两种介电特性均显著提高,这在较高频率下更为相关,此时它们接近稳定值。介电常数超过5,介电损耗因子超过0.04,满足其在电气设备中应用的要求。含10%粉煤灰的配方可保证在0.1 - 4 GHz频域内电磁屏蔽效能至少为99%。粉煤灰含量更高的复合材料能更有效地传导热量,从而提高扩散率和热导率值,显著的热导率值超过0.2 W/(m*K)。最后得出结论,含有10%滑石粉、10%粉煤灰和弹性体的回收高密度聚乙烯复合材料可能是电动汽车部件的最佳选择,符合这些用途的所有要求标准。