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评估废弃电气电子设备 (WEEE) 塑料可回收性的关键因素:芬兰案例研究。

Assessment of critical factors in waste electrical and electronic equipment (WEEE) plastics on the recyclability: A case study in Finland.

机构信息

SCI-MAT Research Platform & Fiber Composite Laboratory, School of Energy Systems, Lappeenranta-Lahti University of Technology, Yliopistonkatu 34, FI-53851 Lappeenranta, Finland.

Fiber Composite Laboratory, School of Energy Systems, Lappeenranta-Lahti University of Technology, Yliopistonkatu 34, FI-53851 Lappeenranta, Finland.

出版信息

Sci Total Environ. 2022 Jul 15;830:155627. doi: 10.1016/j.scitotenv.2022.155627. Epub 2022 May 1.

Abstract

Excessive waste is continually accumulating owing to increased consumption, and an excellent example is the consumption of electrical and electronic equipment (EEE), which are eventually transformed into waste from electrical and electronic equipment (WEEE). WEEE is an interesting material stream because it includes various valuable materials that have great potential for recycling and reutilization. To maximize recycling and utilization potential, all fractions in WEEE must be reviewed from a sustainable perspective. Several WEEE contain plastic, which comprises approximately one-third of the total WEEE composition; thus, this plastic content is a good target for recycling purposes. However, the recycling of WEEE plastics might include some challenges, such as the treatment of harmful substances in the material, which can prevent effective and high-quality material recycling. This study investigates the polymer composition and critical elements of the material stream of WEEE polymer. These polymers were identified using portable near-infrared (NIR) spectroscopy and energy-dispersive X-ray spectroscopy (EDS) at an elemental level. The results showed that among various other polymers, acrylonitrile butadiene styrene (ABS) was the main polymer identified in WEEE. The proportion of unidentified polymers was alarmingly large; specifically, when the presence of bromine was positively correlated with the presence of an unidentified WEEE polymer. This study also corroborated that bromine is actually not present in bromine-free plastics, demonstrating that industrial classification works with WEEE polymers.

摘要

由于消费的增加,过量的废物不断积累,而电器和电子设备(EEE)的消费就是一个很好的例子,这些设备最终会变成电子废物(WEEE)。WEEE 是一种很有趣的材料流,因为它包含了各种有价值的材料,具有很大的回收和再利用潜力。为了最大限度地提高回收和利用潜力,必须从可持续的角度对 WEEE 的所有部分进行审查。一些 WEEE 含有塑料,约占 WEEE 总组成的三分之一;因此,这种塑料含量是回收利用的一个很好的目标。然而,WEEE 塑料的回收可能会遇到一些挑战,例如处理材料中的有害物质,这可能会阻碍有效和高质量的材料回收。本研究调查了 WEEE 聚合物材料流的聚合物组成和关键元素。这些聚合物是使用便携式近红外(NIR)光谱和能量色散 X 射线光谱(EDS)在元素水平上识别的。结果表明,在各种其他聚合物中,丙烯腈丁二烯苯乙烯(ABS)是 WEEE 中主要识别的聚合物。未识别聚合物的比例惊人地大;具体来说,当溴的存在与未识别的 WEEE 聚合物的存在呈正相关时。本研究还证实,溴实际上不存在于无溴塑料中,这表明工业分类适用于 WEEE 聚合物。

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