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木质素纤维与硫酸钠对水泥稳定土力学性能及微观结构的协同作用

Synergistic Effects of Lignin Fiber and Sodium Sulfate on Mechanical Properties and Micro-Structure of Cement-Stabilized Soil.

作者信息

Wang Liang, Na Binbin, Chen Wenhua

机构信息

Institute of Disaster Prevention Engineering, Zhejiang Institute of Hydraulics and Estuary (Zhejiang Institute of Marine Planning and Design), Hangzhou 310020, China.

School of Civil Engineering and Architecture, Zhejiang Sci-Tech University, Hangzhou 310018, China.

出版信息

Materials (Basel). 2025 Aug 22;18(17):3929. doi: 10.3390/ma18173929.

Abstract

This study aims to develop environmentally friendly soil-stabilization materials by investigating the synergistic enhancement mechanism of industrial by-product lignin fibers (LFs) and sodium sulfate (NaSO) on the mechanical and micro-structural properties of cement-stabilized soil. A systematic evaluation was conducted through unconfined compressive strength (UCS), splitting tensile strength, and capillary water absorption tests, supplemented by microscopic analyses including XRD and SEM. The results indicate that the optimal synergistic effect occurs at 1.0% LF and 0.10% NaSO, which increases UCS and splitting tensile strength by 9.23% and 18.37%, respectively, compared to cement-stabilized soil. Meanwhile, early strength development is accelerated. Microscopically, LF physically bridges soil particles, forming aggregates, reducing porosity, and enhancing cohesion. Chemically, NaSO acts as an activator, accelerating cement hydration and stimulating pozzolanic reactions to form calcium aluminosilicate hydrate and gypsum, which fill pores and densify the matrix. The synergistic mechanism lies in NaSO enhancing the interaction between the LFs and clay minerals through ion exchange, facilitating the formation of a stable spatial network structure that inhibits particle sliding and crack propagation. This technology offers substantial sustainability benefits by utilizing paper-making waste LF and low-cost NaSO to improve soil strength, toughness, and impermeability.

摘要

本研究旨在通过研究工业副产品木质素纤维(LFs)和硫酸钠(NaSO)对水泥稳定土力学性能和微观结构性能的协同增强机制,开发环保型土壤稳定材料。通过无侧限抗压强度(UCS)、劈裂抗拉强度和毛细吸水试验进行了系统评估,并辅以XRD和SEM等微观分析。结果表明,在LF含量为1.0%和NaSO含量为0.10%时,协同效应最佳,与水泥稳定土相比,UCS和劈裂抗拉强度分别提高了9.23%和18.37%。同时,早期强度发展加快。微观上,LF在土壤颗粒间形成物理桥接,形成团聚体,降低孔隙率,增强内聚力。化学上,NaSO作为活化剂,加速水泥水化并激发火山灰反应,形成水化硅酸钙和石膏,填充孔隙并使基体致密化。协同机制在于NaSO通过离子交换增强了LF与粘土矿物之间的相互作用,促进了稳定空间网络结构的形成,抑制了颗粒滑动和裂纹扩展。该技术通过利用造纸废料LF和低成本的NaSO提高土壤强度、韧性和抗渗性,提供了显著的可持续性效益。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/63c4/12429758/9ff4c6323300/materials-18-03929-g001.jpg

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