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超越偶氮苯的光开关：初学者指南。

Photoswitches beyond azobenzene: a beginner's guide.

作者信息

Marcon Michela, Haag Christoph, König Burkhard

机构信息

Institute of Organic Chemistry, University of Regensburg, Universitätsstr. 31, 93053 Regensburg, Germany.

出版信息

Beilstein J Org Chem. 2025 Sep 8;21:1808-1853. doi: 10.3762/bjoc.21.143. eCollection 2025.

DOI:10.3762/bjoc.21.143
PMID:40959513
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12434931/
Abstract

Approaching the vast, colourful world of photoswitches from a different field of study or as an undergraduate student may be overwhelming: azobenzene is undoubtedly the most famous due to its easy synthesis and the extensively studied properties. However, there are several photoswitch classes beyond azobenzene with interesting properties that can be tailored to meet one's needs. In this tutorial review, we aim to explain the important terminology and discuss the synthesis, switching mechanisms, and properties of seven interesting photoswitch classes, namely azoheteroarenes, diazocines, indigoid photoswitches, arylhydrazones, diarylethenes, fulgides, and spiropyrans.

摘要

从不同的研究领域或者作为一名本科生去接触光开关这个广阔多彩的世界，可能会让人应接不暇：偶氮苯无疑是最著名的，因其易于合成且性质得到了广泛研究。然而，除了偶氮苯之外，还有几类具有有趣性质的光开关，其性质可以根据需求进行定制。在本教程综述中，我们旨在解释重要的术语，并讨论七类有趣光开关的合成、开关机制和性质，这七类光开关分别是氮杂芳基偶氮化合物、二氮杂萘、靛类光开关、芳基腙、二芳基乙烯、俘精酸酐和螺吡喃。

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本文引用的文献

1
Switching Sides: Regiochemistry and Functionalization Dictate the Photoswitching Properties of Imines.改变方向：区域化学和官能团化决定亚胺的光开关性质。
Angew Chem Int Ed Engl. 2025 Jan 15;64(3):e202415464. doi: 10.1002/anie.202415464. Epub 2024 Nov 2.
2
Photoswitchable imines: aryliminopyrazoles quantitatively convert to long-lived -isomers with visible light.可光开关亚胺：芳基亚胺吡唑在可见光作用下定量转化为寿命较长的反式异构体。
Chem Sci. 2024 Feb 14;15(11):3872-3878. doi: 10.1039/d3sc05841g. eCollection 2024 Mar 13.
3
Multiplicity-driven photochromism controls three-state fulgimide photoswitches.
多重性驱动的光致变色控制三态俘精酰亚胺光开关。
Chem Commun (Camb). 2024 Apr 2;60(28):3774-3777. doi: 10.1039/d3cc05975h.
4
Naphthopyran molecular switches and their emergent mechanochemical reactivity.萘并吡喃分子开关及其新出现的机械化学反应性。
Chem Sci. 2023 Aug 24;14(37):10041-10067. doi: 10.1039/d3sc03729k. eCollection 2023 Sep 27.
5
Proton-Coupled Photochromic Hemithioindigo: Toward Photoactivated Chemical Sensing and Imaging.质子耦合光致变色半硫靛蓝：迈向光活化化学传感与成像
Anal Chem. 2023 Aug 8;95(31):11664-11671. doi: 10.1021/acs.analchem.3c01504. Epub 2023 Jul 26.
6
Photoisomerization of 2-Arylazoimidazoles under Visible Light: Identifying a Predictive Tool to Anticipate and Tune Likely Photoswitching Performance and Cis Half-Life.可见光下 2-芳基偶氮咪唑的光异构化：确定一种预测工具，以预测和调整可能的光开关性能和顺式半衰期。
J Org Chem. 2023 Jul 7;88(13):8236-8247. doi: 10.1021/acs.joc.3c00211. Epub 2023 Jun 27.
7
A cross-conjugation approach for high-performance diaryl-hemithioindigo photoswitches.一种用于高性能二芳基半硫代靛蓝光开关的交叉共轭方法。
Chem Sci. 2023 May 1;14(21):5734-5742. doi: 10.1039/d2sc06939c. eCollection 2023 May 31.
8
A Blueprint for Transforming Indigos to Photoresponsive Molecular Tools.将靛蓝转变为光响应分子工具的蓝图。
Chemistry. 2023 Aug 1;29(43):e202300981. doi: 10.1002/chem.202300981. Epub 2023 May 22.
9
Phenylazothiazoles as Visible-Light Photoswitches.作为可见光光开关的苯基偶氮噻唑。
J Am Chem Soc. 2023 Apr 26;145(16):9072-9080. doi: 10.1021/jacs.3c00609. Epub 2023 Apr 12.
10
A Modern Look at Spiropyrans: From Single Molecules to Smart Materials.螺吡喃的现代视角：从单分子到智能材料
Top Curr Chem (Cham). 2023 Jan 10;381(1):8. doi: 10.1007/s41061-022-00417-2.