Islam Md Mainul, Chowdhury Sutirtha, Khan Md Sefat
Centre for Future Materials, Institute for Advanced Engineering and Space Sciences, University of Southern Queensland, Toowoomba, QLD 4350, Australia.
School of Engineering, University of Southern Queensland, Toowoomba, QLD 4350, Australia.
Materials (Basel). 2025 Sep 18;18(18):4369. doi: 10.3390/ma18184369.
Growing environmental concerns and the depletion of fossil-based resources have accelerated the demand for sustainable alternatives in engineering and construction materials. Among these, bio-based composites have gained attention for their use of renewable and eco-friendly resources. Macadamia nutshells, typically treated as agricultural waste, possess high strength, brittleness, heat resistance, and fracture toughness, making them attractive candidates for structural applications. Australia alone contributes nearly 40% of global macadamia production, generating significant shell by-products that could be repurposed into high-value composites. This study investigates the development of novel composite cores and sandwich structures using macadamia nutshell particles reinforced in an epoxy polymer matrix. Two weight ratios (10% and 15%) and two particle sizes (200-600 µm and 1-1.18 mm) were employed, combined with laminating epoxy resin and hardener to fabricate composite cores. These cores were further processed into sandwich specimens with carbon fabric skins. Flexural and short beam shear (SBS) tests were conducted to evaluate the mechanical behaviour of the composites. The results demonstrate that higher filler content with fine particles achieved up to 15% higher flexural strength and 18% higher stiffness compared to coarser particle composites. Sandwich structures exhibited markedly improved interlaminar shear strength (8-15 MPa), confirming superior load transfer and durability. The results demonstrate that higher filler content and finer particles provided the most favourable mechanical performance, showing higher flexural strength, stiffness, and shear resistance compared to coarser particle formulations. Sandwich structures significantly outperformed core-only composites due to improved load transfer and resistance to bending and shear stresses, with the 15% fine-particle configuration emerging as the optimal formulation. By transforming macadamia nutshells into value-added composites, this research highlights an innovative pathway for waste utilisation, reduced environmental impact, and sustainable material development. The findings suggest that such composites hold strong potential for structural applications in construction and related engineering fields, especially in regions with abundant macadamia production. This study reinforces the role of agricultural by-products as practical solutions for advancing green composites and contributing to circular economy principles.
对环境问题的日益关注以及化石资源的枯竭,加速了工程和建筑材料领域对可持续替代品的需求。其中,生物基复合材料因其使用可再生和环保资源而受到关注。澳洲坚果壳通常被视为农业废弃物,具有高强度、脆性、耐热性和断裂韧性,使其成为结构应用的有吸引力的候选材料。仅澳大利亚就贡献了全球近40%的澳洲坚果产量,产生了大量的壳副产品,这些副产品可以重新利用制成高价值的复合材料。本研究调查了使用在环氧树脂基体中增强的澳洲坚果壳颗粒开发新型复合芯材和夹层结构。采用了两种重量比(10%和15%)和两种粒径(200 - 600 µm和1 - 1.18 mm),并与层压环氧树脂和固化剂结合来制造复合芯材。这些芯材进一步加工成带有碳纤维织物蒙皮的夹层试件。进行了弯曲和短梁剪切(SBS)试验以评估复合材料的力学性能。结果表明,与粗颗粒复合材料相比,具有细颗粒的较高填料含量实现了高达15%的弯曲强度提高和18%的刚度提高。夹层结构表现出显著提高的层间剪切强度(8 - 15 MPa),证实了优异的载荷传递和耐久性。结果表明,较高的填料含量和较细的颗粒提供了最有利的力学性能,与粗颗粒配方相比,表现出更高的弯曲强度、刚度和抗剪强度。夹层结构由于改善了载荷传递以及对弯曲和剪切应力的抵抗力,明显优于仅芯材的复合材料,15%细颗粒配置成为最佳配方。通过将澳洲坚果壳转化为增值复合材料,本研究突出了一条创新的废物利用途径、减少环境影响以及可持续材料开发。研究结果表明,此类复合材料在建筑和相关工程领域的结构应用中具有强大潜力,特别是在澳洲坚果产量丰富的地区。本研究强化了农业副产品作为推进绿色复合材料和促进循环经济原则的实际解决方案的作用。