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用于可持续包装和多功能应用的纳米片-碳纳米管增强聚丁二酸丁二醇酯纳米复合材料的性能提升

Enhanced performance of nanoplate-carbon nanotube reinforced poly(butylene succinate) nanocomposites for sustainable packaging and multifunctional applications.

作者信息

Tsou Chi-Hui, Huang Xin, Ge Fei-Fan, Lin Jarrn-Horng, Potiyaraj Pranut, Preuksarattanawut Charasphat, Yang Tao, Hu Xue-Fei

机构信息

Material Corrosion and Protection Key Laboratory of Sichuan Province, School of Materials Science and Engineering, Sichuan University of Science and Engineering, Zigong 643000, China.

Department of Petrochemistry and Polymer Science, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand.

出版信息

Food Chem X. 2025 Sep 9;31:102989. doi: 10.1016/j.fochx.2025.102989. eCollection 2025 Oct.

Abstract

This study developed modified poly (butylene succinate) (MPBS) nanocomposites reinforced with ZnO nanoplate-decorated carbon nanotubes (CNT-ZNP) to improve mechanical, thermal, and functional properties for food packaging applications. MPBS was synthesized via grafting of maleic anhydride to enhance compatibility with nanofillers. Incorporation of only 0.1 g/hg CNT-ZNP led to substantial improvements in tensile strength (36.5 %), elongation at break (108.6 %), and yield strength (41.6 %), demonstrating that enhanced performance can be achieved with minimal nanofiller content. The nanocomposite also exhibited enhanced crystallinity, thermal stability, and water vapor barrier performance. Food preservation tests demonstrated that MPBS/CNT-ZNP films effectively maintained banana freshness over 14 days and inhibited microbial growth in raw chicken for up to 108 h. These outcomes highlight the material's potential to extend shelf life and reduce spoilage in perishable products. Overall, the MPBS/CNT-ZNP nanocomposites combine mechanical robustness with antimicrobial and preservation functionality, supporting their application as sustainable and multifunctional food packaging films.

摘要

本研究制备了用氧化锌纳米片修饰的碳纳米管(CNT-ZNP)增强的改性聚丁二酸丁二醇酯(MPBS)纳米复合材料,以改善其机械、热学和功能性能,用于食品包装应用。通过马来酸酐接枝合成MPBS,以增强与纳米填料的相容性。仅加入0.1 g/hg的CNT-ZNP就能使拉伸强度(提高36.5%)、断裂伸长率(提高108.6%)和屈服强度(提高41.6%)得到显著改善,这表明只需极少的纳米填料含量就能实现性能增强。该纳米复合材料还表现出增强的结晶度、热稳定性和水蒸气阻隔性能。食品保鲜测试表明,MPBS/CNT-ZNP薄膜能在14天内有效保持香蕉的新鲜度,并在长达108小时内抑制生鸡肉中的微生物生长。这些结果突出了该材料在延长易腐产品保质期和减少变质方面的潜力。总体而言,MPBS/CNT-ZNP纳米复合材料兼具机械强度和抗菌及保鲜功能,支持其作为可持续的多功能食品包装薄膜的应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82ed/12475868/e61dd7ff436c/ga1.jpg

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