Iwasaki K
Sangyo Igaku. 1979 Jan;21(1):36-46. doi: 10.1539/joh1959.21.36.
Textiles are used so widely as interior materials of many buildings, houses, and transportation facilities, that the combustion gas has a chance of intoxication of a fire accident. Therefore this investigation was undertaken to clarify the toxicity of the gas and to obtain an index for safety standards in such cases. The combustion gases of cotton, polypropylene, acrylic, flame retardant (F.R.) cotton and F.R. acrylic fabrics were analyzed by a gas chromatograph and a GC-Mass spectorograph, and also tested with experimental animals to determine the lethal factors including blood gas analyzing technique. The gas exposuring test based on gas analysis data showed that the toxicity of these combustion products increased in the following orders: cotton, polypropylene, F.R. cotton, F.R. acrylic and acrylic. Comparative indices of the toxicity showed that acrylic increased 7.26-fold as compared with that of cotton. It was recognized that the lethal factors in the mice was due to carbon monoxide and/or hydrogen cyanide during the exposure one hour, and that sequelae due to acrolein during the seven day observation period after the exposure. Flame retardant treatment increased twice the toxicity of cotton. On the contrary, that of acrylic was reduced by 0.8 time compared with the original fabric, so that the treatment could be recommended only in case of acrylic from the safety standpoint. From the above results, it can be stressed that vigorous smoke exhaust procedure should be executed in the case of fire accidents for saving human lives.
纺织品被广泛用作许多建筑物、房屋和交通设施的内部材料,以至于火灾事故产生的燃烧气体有可能使人中毒。因此,开展了这项调查,以阐明该气体的毒性,并获取此类情况下安全标准的指标。采用气相色谱仪和气相色谱 - 质谱联用仪对棉花、聚丙烯、腈纶、阻燃棉和阻燃腈纶织物的燃烧气体进行了分析,并对实验动物进行了测试,以确定包括血气分析技术在内的致死因素。基于气体分析数据的气体暴露试验表明,这些燃烧产物的毒性按以下顺序增加:棉花、聚丙烯、阻燃棉、阻燃腈纶和腈纶。毒性的比较指数表明,腈纶的毒性与棉花相比增加了7.26倍。据确认,在暴露一小时期间,小鼠的致死因素是一氧化碳和/或氰化氢,而在暴露后七天的观察期内,致死因素是丙烯醛。阻燃处理使棉花的毒性增加了一倍。相反,腈纶的毒性与原织物相比降低了0.8倍,因此从安全角度来看,仅在腈纶的情况下才建议进行这种处理。从上述结果可以强调,在火灾事故中应执行强力排烟程序以挽救生命。