Wrona M Z, Dryhurst G
Biochim Biophys Acta. 1979 Oct 11;570(2):371-87. doi: 10.1016/0005-2744(79)90157-8.
The electrochemical oxidation of a number of N-methylated uric acids at the pyrolytic graphite and gold electrodes has been compared to their enzymic oxidation with type VIII peroxidase and H2O2. Spectral, electroanalytical and kinetic evidence supports the conclusion that for all compounds the electrochemical and enzymic reactions proceed by identical mechanisms.
已将多种N-甲基化尿酸在热解石墨电极和金电极上的电化学氧化与它们在VIII型过氧化物酶和过氧化氢作用下的酶促氧化进行了比较。光谱、电分析和动力学证据支持以下结论:对于所有化合物,电化学反应和酶促反应的进行机制相同。