氧代烯酸作为儿茶酚细菌降解过程中的代谢产物。
Oxoenoic acids as metabolites in the bacterial degradation of catechols.
作者信息
Bayly R C, Dagley S
出版信息
Biochem J. 1969 Feb;111(3):303-7. doi: 10.1042/bj1110303.
Abstract
- Partially purified extracts of a Pseudomonas converted the meta ring-fission product of 4-methylcatechol into a compound having spectroscopic and chemical properties consistent with its being 2-oxohex-4-enoic acid. 2. Catechol and 3-methylcatechol were both metabolized to a compound that appeared to be 2-oxopent-4-enoic acid. 3. Solutions of norvaline and norleucine were prepared from these metabolites. 4. A reaction scheme is presented for the conversion of catechols into hydroxyoxo acids after meta ring-fission.
摘要
- 一种假单胞菌的部分纯化提取物将4-甲基邻苯二酚的间位环裂解产物转化为一种化合物，该化合物的光谱和化学性质表明它是2-氧代己-4-烯酸。2. 邻苯二酚和3-甲基邻苯二酚均被代谢为一种似乎是2-氧代戊-4-烯酸的化合物。3. 由这些代谢产物制备了正缬氨酸和正亮氨酸溶液。4. 提出了一个反应方案，用于描述邻苯二酚在间位环裂解后转化为羟基氧代酸的过程。
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