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化学动力学:环境中化学物质的迁移与行为——环境卫生领域的一个问题

Chemodynamics: transport and behavior of chemicals in the environment--a problem in environmental health.

作者信息

Freed V H, Chiou C T, Haque R

出版信息

Environ Health Perspect. 1977 Oct;20:55-70. doi: 10.1289/ehp.772055.

Abstract

In the manufacture and use of the several thousand chemicals employed by technological societies, portions of these chemicals escape or are intentionally introduced into the environment. The behavior, fate, and to some extent the effects produced by these chemicals are a result of a complex interaction of the properties of the chemical with the various processes governing transport, degradation, sequestration, and uptake by organisms. In addition, such processes as adsorption, evaporation, partitioning, and degradation are influenced by ambient conditions of temperature, air movement, moisture, presence of other chemicals, and the concentration and properties of the subject chemicals. These influence the level and extent of exposure to these chemicals that man might receive. Study of the physiochemical properties and extent of exposure to these chem;cals that man might receive. Study of the physiochemical properties of compounds in relation to these various processes has provided a basis for better understanding of the quantitative behavior. Such information is useful in development of predictive models on behavior and fate of the chemicals in relation to human exposure. Beyond this, it provides information that could be used to devise procedures of manufacture, use, and disposal that would minimize environmental contamination. Some of the physical principles involved in chemodynamics are presented in this review.

摘要

在技术社会所使用的数千种化学品的制造和使用过程中,这些化学品的一部分会逸出或被有意引入环境。这些化学品的行为、归宿以及在某种程度上产生的影响,是化学品性质与控制其传输、降解、固存及被生物体吸收的各种过程之间复杂相互作用的结果。此外,诸如吸附、蒸发、分配和降解等过程会受到温度、空气流动、湿度、其他化学品的存在以及目标化学品的浓度和性质等环境条件的影响。这些因素会影响人类可能接触到的这些化学品的暴露水平和程度。对人类可能接触到的这些化学品的理化性质及暴露程度的研究。对化合物理化性质与这些不同过程关系的研究,为更好地理解其定量行为提供了基础。此类信息对于开发与人类暴露相关的化学品行为和归宿的预测模型很有用。除此之外,它还提供了可用于设计制造、使用和处置程序的信息,这些程序将最大限度地减少环境污染。本综述介绍了化学动力学中涉及的一些物理原理。

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