Ebner H, Luger T, Binder R, Machata G
Wien Klin Wochenschr. 1978 Apr 28;90(9):311-3.
The 6 most common fluid and powder detergent brands in use in Austria were analyzed as to their nickel and chromium content. The analysis was carried out by means of atomic absorption spectroscopy. 1. The above-mentioned metals were found to be present in each of the products analysed. On average, the fluid detergents contained ten times less nickel and chromium than the powders. 2. Repeated investigations revealed a considerable variation in metal ion content in different batches of the same detergent. Thus, presumably the raw products already contain nickel and chromium and it is unlikely that these ions get into the products during the manufacturing process. 3. In the appropriately diluted detergent powder solutions, as recommended by the producer, the content of nickel was found to lie between 0.4 ppm and 0.717 ppm and the chromium content ranged from 0.733 to 0.917 ppm. Since powder detergents also contain complex-producing agents, it can be assumed that these concentrations of metal ions do not suffice for sensitization. In the fluid detergents the nickel and chromium contents were found to be below the safety limit for the elicitation of an excematous reaction.
对奥地利使用的6种最常见的液体和粉末洗涤剂品牌的镍和铬含量进行了分析。分析采用原子吸收光谱法进行。1. 在分析的每种产品中均发现了上述金属。平均而言,液体洗涤剂中的镍和铬含量比粉末洗涤剂少十倍。2. 反复调查显示,同一洗涤剂不同批次的金属离子含量存在相当大的差异。因此,推测原材料中已含有镍和铬,并且这些离子在制造过程中进入产品的可能性不大。3. 在按照生产商建议适当稀释的洗涤剂粉末溶液中,发现镍含量在0.4 ppm至0.717 ppm之间,铬含量在0.733至0.917 ppm之间。由于粉末洗涤剂还含有络合剂,可以假定这些金属离子浓度不足以引起过敏。在液体洗涤剂中,镍和铬含量低于引发湿疹反应的安全限值。