Digernes V, Astrup E G
Int Arch Occup Environ Health. 1982 Feb;49(3-4):193-7. doi: 10.1007/BF00377928.
The use of polychlorinated biphenyls (PCBs) restricted to closed systems. They are thus still used as dielectric fluids in capacitors and transformers. The hypothesis that skin rashes and excema reported among datascreen operators might be caused by leakage of PCB from components in the screen terminals was investigated. No information about the chemical content of the electric components in the actual datascreen terminals were available. The PCB-concentration in the atmosphere in a workplace where such skin reactions had previously occurred was therefore determined. Air was sampled through 2 or 3 days, during work hours only. A glass fiber backed by an amberlite XAD-2 column was used to trap the sample. The total level of PCBs in this sample was analysed by glass-capillary gas chromatography with electron capture detection. Commercial PCB mixtures were used as standards. PCB-concentrations in the working atmosphere (56-81 ng/M3) were about 50-80 times the level of PCB in samples collected outside the building. Indoor and outdoor samples differed also qualitatively. The indoor samples contained only Aroclor 1242, while the outdoor samples contained a mixture of Aroclor 1242 and 1254. The amounts of PCBs measured were below the safety level for working atmosphere, as recommended by NIOSH in 1977. However, knowing that the samples were collected in an office where there was no known use of PCBs, the levels found were unexpectedly high. Further investigations should therefore be undertaken to clarify whether datascreen terminals might be sources of PCB-contamination.
多氯联苯(PCBs)的使用仅限于封闭系统。因此,它们仍被用作电容器和变压器中的介电液。人们对数据屏幕操作员中报告的皮疹和湿疹可能由屏幕终端部件中的多氯联苯泄漏引起这一假设进行了调查。关于实际数据屏幕终端中电气部件化学成分的信息无法获取。因此,测定了之前曾出现此类皮肤反应的工作场所空气中的多氯联苯浓度。仅在工作时间内对空气进行了两到三天的采样。使用玻璃纤维填充的琥珀石XAD - 2柱来捕集样品。通过带有电子捕获检测的玻璃毛细管气相色谱法分析该样品中多氯联苯的总含量。使用商用多氯联苯混合物作为标准品。工作场所空气中的多氯联苯浓度(56 - 81纳克/立方米)约为建筑物外采集样品中多氯联苯浓度的50 - 80倍。室内和室外样品在质量上也存在差异。室内样品仅含有氯丹1242,而室外样品含有氯丹1242和1254的混合物。所测得的多氯联苯含量低于美国国家职业安全与健康研究所(NIOSH)1977年推荐的工作场所安全水平。然而,鉴于样品是在一个未知有使用多氯联苯情况的办公室采集的,所发现的浓度却出乎意料地高。因此,应进一步开展调查,以澄清数据屏幕终端是否可能是多氯联苯污染的来源。