Gabermann V
Biokhimiia. 1978 Feb;43(2):246-51.
Oscillographic polarography has been applied for the mescaline and pellotine estimation. These alkaloids produce in 0.5 N NaOH electrolyte a sharp peak within the cathode region of the oscillogram, each of them showing different potential. It makes possible to estimate them at a concentration of 5.10(-6) g/ml. All the forms of Lophophora williamsii were found to contain mescaline and lower content of pellothine, L. jourdaniana--to have equal content of both alkaloide, L. diffusa and L. fricii--to contain pellotine and only traces of mescaline. Plants grown in the greenhouse accumulated the same amount of alkaloids as native plants. Grafting on roodstock which does not produce essential amount of the alkaloids, does not affect the ability of Lophophora to synthesize mescaline and pellotine.
示波极谱法已用于麦司卡林和佩洛碱的测定。这些生物碱在0.5N氢氧化钠电解液中,于示波图的阴极区域产生一个尖锐的峰,它们各自显示出不同的电位。这使得能够在5×10⁻⁶克/毫升的浓度下对它们进行测定。发现所有形式的威廉斯氏仙人掌都含有麦司卡林,佩洛汀含量较低;乔丹氏仙人掌——两种生物碱含量相等;散生仙人掌和弗里氏仙人掌——含有佩洛碱,仅含微量麦司卡林。温室中种植的植物积累的生物碱量与原生植物相同。嫁接在不产生必需量生物碱的砧木上,并不影响威廉斯氏仙人掌合成麦司卡林和佩洛碱的能力。