Braszczyńska Z, Linscheid D, Osińska R, Kłopotowski J
Med Pr. 1983;34(5-6):413-7.
Due to a number of cases of acute arsine poisonings in one of zinc metallurgic plants, the environmental concentrations of arsenic compounds were determined. In the technological process of zinc metallurgy, the highest arsine concentrations can occur: a) during zinc refining in the furnace, where, because of the full automatization process, the presence of workers is not necessary, b) during the refining furnace repair--because of the melting loss wetting. Levels of arsenic concentrations, just as cadmium and zinc concentrations, according to the valid hygienic standards, are very low at the shaft furnace and the agglomerating plant. The urinary arsenic concentrations in workers has not exceeded 100 micrograms/l and these results also testify to a small exposure. However, it is necessary to take into account the high lead concentrations at some work-posts, both due to the multiple exceeding of the hygienic standard, and the simultaneous occurrence of lead and arsenic, which create a potential possibility of forming more toxic compounds, e.g. lead arsenide. In view of the carcinogenic exposure, it is important to take into account the possibility of interaction between arsenic and polycyclic aromatic hydrocarbones which occur during coke dry degassing.
由于一家锌冶炼厂发生了多起急性胂中毒事件,因此对砷化合物的环境浓度进行了测定。在锌冶金的工艺流程中,胂浓度可能在以下情况达到最高:a)在炉内精炼锌时,由于是全自动过程,无需工人在场;b)在精炼炉维修期间——因为有熔炼损失的浸湿情况。根据现行卫生标准,竖炉和烧结厂的砷浓度水平以及镉和锌的浓度水平都非常低。工人尿液中的砷浓度未超过100微克/升,这些结果也证明接触程度较低。然而,有必要考虑到一些工作岗位上铅浓度较高的情况,这既是由于多次超过卫生标准,也是由于铅和砷同时存在,这有可能形成毒性更强的化合物,例如砷化铅。鉴于致癌暴露,考虑砷与焦炭干法脱气过程中出现的多环芳烃之间相互作用的可能性很重要。