Schmid E R, Fogy I, Kenndler E
Z Lebensm Unters Forsch. 1978 May 29;166(4):221-4. doi: 10.1007/BF01126547.
The applicability of the specific 3H-radioactivity for the distinction of synthetic and biogenic vinegar was tested. The acetic acid was isolated from the vinegar as calcium acetate, and the calcium acetate was combusted at 830 degrees C to CO2 and H2O. The water was measured either after two destillation steps by liquid scintillation counting or after reduction to hydrogen and reaction to ethane in a gas proportional counter. The difference in the 3H-content between the two types of vinegar in Austria is about 80--100 T.U. Since the level of activity is subject to appreciable annual fluctuations a series of synthetic and biogenic comparison samples always has to be included.
测试了特定的³H放射性在区分合成醋和生物源醋方面的适用性。从醋中以醋酸钙的形式分离出乙酸,然后将醋酸钙在830℃下燃烧生成二氧化碳和水。水要么经过两步蒸馏后通过液体闪烁计数法测量,要么在还原为氢气并在气体比例计数器中与乙烷反应后测量。奥地利两种类型醋之间的³H含量差异约为80 - 100 TU。由于活性水平每年会有明显波动,因此总是必须包含一系列合成和生物源的对照样品。