Alykov N M
Antibiotiki. 1980 Jun;25(6):415-9.
Complexing of rubomycin (H2R) with copper ions (II) in aqueous solutions was studied on the basis of fluorimetric and photometric measurements. H2R interacted with Cu (OH)+ to form the complex CuR with the molar extinction coefficient Ek = 4 . 96 . 10(3) and the stability 1g beta k = 5.54 +/- 0.09. The method of determining H2R in biological materials has been developed. It is based on the ability of the copper entering the complex to extinguish fluorexon luminescence in aqueous solutions.
基于荧光和光度测量研究了柔红霉素(H2R)与水溶液中铜离子(II)的络合作用。H2R与Cu(OH)+相互作用形成络合物CuR,其摩尔消光系数Ek = 4.96×10³,稳定性lgβk = 5.54±0.09。已开发出测定生物材料中H2R的方法。该方法基于进入络合物的铜熄灭水溶液中荧光素发光的能力。