梭状芽孢杆菌降解六氯环己烷过程中形成的中间体的鉴定
Identification of intermediates formed during the degradation of hexachlorocyclohexanes by Clostridium sphenoides.
作者信息
Heritage A D, Rae I C
出版信息
Appl Environ Microbiol. 1977 Jun;33(6):1295-7. doi: 10.1128/aem.33.6.1295-1297.1977.
Abstract
Washed cell suspensions of Clostridium sphenoides degraded the alpha-isomer of 1,2,3,4,5,6-hexachlorocyclohexane via delta-3,4,5,6-tetrachloro-1-cyclohexene and the gamma-isomer via gamma-3,4,5,6-tetrachloro-1-cyclohexene. Both intermediates were further metabolized to unknown substances. The tetrachlorocyclohexene intermediates were identified by gas chromatography and mass spectrometry.
摘要
楔形梭菌的洗涤细胞悬浮液通过δ-3,4,5,6-四氯-1-环己烯降解1,2,3,4,5,6-六氯环己烷的α-异构体，通过γ-3,4,5,6-四氯-1-环己烯降解γ-异构体。两种中间体均进一步代谢为未知物质。通过气相色谱和质谱法鉴定了四氯环己烯中间体。
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