Cope F W
Physiol Chem Phys. 1982;14(5):423-30.
Some organic dyes of a double diazo structure, pressurized into thin films, show trapping of magnetic flux at room temperature, suggestive of the behavior of type 2 superconductors. Some also show switching from low to high electrical conductivity at a voltage threshold, like amorphous inorganic semiconductors. An applied magnetic field facilitates switching, as well as current flow after switching, in a dye that traps magnetic flux but not in a dye of almost similar structure that does not trap magnetic flux. For best results, the magnetic field should be applied before switching and in a direction perpendicular to current flow. The magnetic field effects observed in the dye films at room temperature may be analogous to "anomolous" magnetic phenomena observed in metallic superconductors and/or in superconducting Josephson junctions at low temperatures. The implied possibility of superconductive mechanisms of biomagnetic effects, and apparent relation to the electrical switching seen in wet melanin, give the findings biological relevance.
一些具有双偶氮结构的有机染料,压制成薄膜后,在室温下显示出磁通量俘获现象,这表明其具有2型超导体的行为。一些染料在电压阈值下还会从低电导率切换到高电导率,类似于非晶态无机半导体。施加磁场会促进俘获磁通量的染料发生切换以及切换后的电流流动,但不会促进结构几乎相似但不俘获磁通量的染料发生这些现象。为了获得最佳效果,应在切换之前施加磁场,且磁场方向应垂直于电流方向。在室温下染料薄膜中观察到的磁场效应可能类似于在低温下金属超导体和/或超导约瑟夫森结中观察到的“异常”磁现象。生物磁效应的超导机制的潜在可能性,以及与湿黑色素中电切换的明显关系,赋予了这些发现生物学相关性。