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[卤代烷氧基苯甲酸二仲丁酰胺的植物毒性]

[Phytotoxicity of di,sec.butylamides of halogenoalkoxybenzoic acids].

作者信息

Pagani G, Baruffini A, Caccialanza G, Mazza M

出版信息

Farmaco Sci. 1978 Mar;33(3):189-200.

PMID:738441
Abstract

N,N-di,sec.butylamides of halogenated alkoxybenzoic acids were prepared and tested for phytotoxic activity. The corresponding acids and a series of N-alkyl- and N,N-dialkylamides of 2-methoxy-3,5-dichlorobenzoic acid were studied in parallel. The phytotoxicity of these substances was tested against seven representative weeds and some crop plants using both pre- and post-emergence test at doses of 6 kg/ha or lower. The amides studied proved more strongly phytotoxic on absorption through the root than through the foliage. Furthermore selective phytotoxic activity against two important infesting graminacae, Echinochloa crus-galli R.S. and Setaria glauca L. was observed. Some of these compounds showed low toxicity or were tolerated by crop plants. The results obtained with this series of amides of 2-methoxy-3,5-dichlorobenzoic acid confirm the importance of the sec.butyl group on N for the appearance of selective phytotoxicity.

摘要

制备了卤代烷氧基苯甲酸的N,N - 二仲丁基酰胺,并对其进行了植物毒性活性测试。同时研究了相应的酸以及一系列2 - 甲氧基 - 3,5 - 二氯苯甲酸的N - 烷基和N,N - 二烷基酰胺。使用6千克/公顷或更低剂量的苗前和苗后试验,针对七种代表性杂草和一些农作物测试了这些物质的植物毒性。所研究的酰胺经根部吸收时的植物毒性比经叶部吸收时更强。此外,还观察到对两种重要的禾本科杂草稗草和金色狗尾草具有选择性植物毒性活性。这些化合物中的一些显示出低毒性或能被农作物耐受。用这一系列2 - 甲氧基 - 3,5 - 二氯苯甲酸酰胺所获得的结果证实了N上仲丁基对于选择性植物毒性出现的重要性。

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