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炭黑的溶剂提取物——可提取物总量的测定及苯并(α)芘的分析

Solvent extracts of carbon black--determination of total extractables and analysis for benzo(alpha)pyrene.

作者信息

Taylor G T, Redington T E, Bailey M J, Buddingh F, Nau C A

出版信息

Am Ind Hyg Assoc J. 1980 Nov;41(11):819-25. doi: 10.1080/15298668091425699.

DOI:10.1080/15298668091425699
PMID:7457372
Abstract

The efficiency of three organic solvents for extraction of adsorbates, including polycyclic aromatic hydrocarbons (PAH), on five rubber-grade oil furnace blacks was studied. Measurement of both the percent total extractables and the specific PAH, benzo(alpha)pyrene (B alpha P), showed toluene to be a better extractant than benzene and both to be superior to cyclohexane. Spectral analysis for B alpha P was preceded by chromatographic separation. A thin layer technique was shown to be a rapid and reliable replacement for paper chromatography.

摘要

研究了三种有机溶剂从五种橡胶级油炉黑中萃取吸附质(包括多环芳烃,PAH)的效率。对总可萃取物百分比和特定PAH苯并(α)芘(BαP)的测量表明,甲苯是比苯更好的萃取剂,且二者都优于环己烷。对BαP进行光谱分析之前需进行色谱分离。结果表明,薄层技术是一种快速且可靠的纸色谱替代方法。

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