Cheng B, Scheidt W R
Department of Chemistry and Biochemistry, University of Notre Dame, IN 46556, USA.
Acta Crystallogr C. 1995 May 15;51 ( Pt 5):825-8. doi: 10.1107/s0108270194013181.
The crystal structure of [Mn(OEP)(OClO3)] (where OEP = C36H44N4) has been determined. The axial Mn-O bond length is 2.183 (2) A and the equatorial Mn-Np bond lengths have an average value of 2.000 (5) A. The molecules form weak dimers in the solid state with interring distances of 3.49 A and a lateral shift of 3.27 A. The compound is found to be isomorphous with the iron derivative [Fe(OEP)(OClO3)]. A brief comparison of the structural parameters for the two molecules is given.
已确定[Mn(OEP)(OClO₃)]（其中OEP = C₃₆H₄₄N₄）的晶体结构。轴向Mn - O键长为2.183(2) Å，赤道面Mn - Np键长的平均值为2.000(5) Å。分子在固态中形成弱二聚体，相互间距为3.49 Å，横向位移为3.27 Å。发现该化合物与铁衍生物[Fe(OEP)(OClO₃)]同晶型。给出了这两种分子结构参数的简要比较。
