Vardev P
Probl Khig. 1993;18:143-56.
In order to define the mean shift exposure of workers in the environment of hydrogen chloride, we could use, besides long-term colorimetric tubes also colorimetric tubes on the principle of diffusion, named also passive monitors. Experiments are performed on different reactionary principles and recipes of indicator compositions for hydrogen chloride: with pH-indicators as bromphenol blau, dimethyl yellow and benzopurpurine 4B, and also reactions for discoloration of silver chromate or lead sulfate. The successful variants are metrologically evaluated by means of gas generating device for calibration gas mixtures. Special attention is given to the accuracy of the results at different air humidity. Recipes with minimum effect of the air humidity on the results are developed and is proved, that concentrations of hydrogen chloride could be significantly measured, also at higher humidity of the examined air of those given in the literature.
为了确定在氯化氢环境中工人的平均接触剂量,除了长期使用比色管外,我们还可以使用基于扩散原理的比色管,也称为被动监测器。针对氯化氢,根据不同的反应原理和指示剂组合物配方进行了实验:使用pH指示剂,如溴酚蓝、二甲基黄和苯并紫嘌呤4B,以及铬酸银或硫酸铅褪色反应。通过用于校准气体混合物的气体发生装置对成功的变体进行计量评估。特别关注不同空气湿度下结果的准确性。开发了对结果受空气湿度影响最小的配方,并证明在高于文献中给出的被检测空气湿度条件下,也能够显著测量氯化氢浓度。