蔓生百部碱A的立体结构以及蔓生百部碱A和硬脂酰天鹅绒菌素在人唾液作用下转化为辣味化合物的过程。

Stereostructure of plagiochiline A and conversion of plagiochiline A and stearoylvelutinal into hot-tasting compounds by human saliva.

作者信息

Hashimoto T, Tanaka H, Asakawa Y

机构信息

Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Japan.

出版信息

Chem Pharm Bull (Tokyo). 1994 Jul;42(7):1542-4. doi: 10.1248/cpb.42.1542.

DOI:10.1248/cpb.42.1542

PMID:7923476

Abstract

The stereostructure of plagiochiline A (1) isolated from the liverwort Plagiochila fruticosa has been established by X-ray crystallographic analysis. Plagiochiline A was converted into plagiochilal B (2) and furanoplagiochilal (3) by human saliva, and stearoylvelutinal (4) isolated from the fungus Lactarius vellerus was converted into velleral (5), also by human saliva.

摘要

通过X射线晶体学分析确定了从地钱类植物小果斜蒴藓中分离出的斜蒴藓素A（1）的立体结构。斜蒴藓素A经人唾液转化为斜蒴藓醛B（2）和呋喃斜蒴藓醛（3），从真菌乳白红菇中分离出的硬脂酰绒毛草醛（4）也经人唾液转化为绒毛草醛（5）。