Bäckman P, Bastos M, Hallén D, Lönnbro P, Wadsö I
Division of Thermochemistry, University of Lund, Sweden.
J Biochem Biophys Methods. 1994 Mar;28(2):85-100. doi: 10.1016/0165-022x(94)90023-x.
Seven heat conduction calorimeters have been evaluated in terms of sensitivity and thermal response time. The use of a dynamic method to correct for the thermal inertia of the calorimeter is shown to reduce by one order of magnitude the time required to conduct a stepwise titration experiment involving a fast reaction. The ability to determine association constants of strong 1:1 complexes has been evaluated in terms of the precision of determining thermal energy.
已对七台热传导量热计的灵敏度和热响应时间进行了评估。结果表明，使用动态方法校正量热计的热惯性可将进行涉及快速反应的逐步滴定实验所需的时间减少一个数量级。已根据测定热能的精度评估了测定强1:1配合物缔合常数的能力。
