Bastos M, Hägg S, Lönnbro P, Wadsö I
Division of Thermochemistry, University of Lund, Sweden.
J Biochem Biophys Methods. 1991 Oct-Nov;23(3):255-8. doi: 10.1016/0165-022x(91)90018-r.
Thermopile heat conduction calorimeters normally have high time constants. Multistep titration experiments involving fast processes may then require several hours to perform. It is demonstrated that such experiments can be conducted about 10 times faster, without loss of accuracy, by use of a "dynamic correction method". For a new small vessel thermopile conduction calorimeter, injections can be made at 1.5-min intervals.