Stereostructure and NMR characterization of the antibiotic candidin.
作者信息
Pawlak J, Sowiński P, Borowski E, Gariboldi P
机构信息
Department of Pharmaceutical Technology and Biochemistry, Technical University of Gdańsk, Poland.
出版信息
J Antibiot (Tokyo). 1993 Oct;46(10):1598-604. doi: 10.7164/antibiotics.46.1598.
PMID:8244889
Abstract
The stereostructure of the heptaene macrolide antibiotic candidin was established on the basis of NMR studies: 13C, DQF-COSY, ROESY and C,H-COSY experiments. The absolute configuration of the candidin chiral centers were assigned as 3R, 5S, 10R, 11R, 13R, 15S, 16R, 17S, 19S, 34S, 35R, 36R and 37S.
摘要
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