Stereostructure of Rimocidin.
作者信息
Sowiński P, Pawlak J, Borowski E, Gariboldi P
机构信息
Department of Drug Technology and Biochemistry, Technical University of Gdańsk, Poland.
出版信息
J Antibiot (Tokyo). 1995 Nov;48(11):1288-91. doi: 10.7164/antibiotics.48.1288.
PMID:8557570
Abstract
NMR studies of rimocidin, consisting of DQF-COSY, ROESY, HSQC, HMBC and 1D-TOCSY experiments, resulted in the assignment of the absolute configuration of the rimocidin chiral centers as 2S, 3R, 9S, 11R, 13S, 14R, 15S, 17R, and 27R. The geometry of tetraene chromophore was found to be all-trans.
摘要
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