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基于磷光寿命猝灭并采用聚合物固定化金属卟啉探针的光学氧传感器。第2部分。传感膜及结果。

Optical oxygen sensor based on phosphorescence lifetime quenching and employing a polymer immobilised metalloporphyrin probe. Part 2. Sensor membranes and results.

作者信息

Gewehr P M, Delpy D T

机构信息

Department of Medical Physics & Bioengineering, University College London, UK.

出版信息

Med Biol Eng Comput. 1993 Jan;31(1):11-21. doi: 10.1007/BF02446880.

DOI:10.1007/BF02446880
PMID:8326758
Abstract

A gaseous oxygen sensor is described based on the measurement of phosphorescence lifetime of the dye palladium coproporphyrin, immobilised in a range of membrane materials including polyvinyl chloride, polymethylmethacrylate, polystyrene and silicone rubber. The lifetime of the dye in these materials is described, measured using a simple system consisting of a pulsed xenon flash lamp light source and a PC-based data acquisition system. The linearity of the sensing membranes over the 0-100 per cent oxygen range is presented together with data on temperature sensitivity, the effects of CO2, N2O, H2O and halothane, and the effects of ageing over a 90 day period. The sensors based upon polystyrene immobilised dye appear to provide the optimum characteristics for a gaseous oxygen sensor.

摘要

描述了一种基于测量固定在包括聚氯乙烯、聚甲基丙烯酸甲酯、聚苯乙烯和硅橡胶在内的一系列膜材料中的染料钯原卟啉磷光寿命的气态氧传感器。描述了该染料在这些材料中的寿命,并使用由脉冲氙闪光灯光源和基于PC的数据采集系统组成的简单系统进行测量。给出了传感膜在0 - 100%氧气范围内的线性度,以及关于温度敏感性、二氧化碳、一氧化二氮、水和氟烷的影响以及90天老化影响的数据。基于固定在聚苯乙烯上的染料的传感器似乎为气态氧传感器提供了最佳特性。

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Optical oxygen sensor based on phosphorescence lifetime quenching and employing a polymer immobilised metalloporphyrin probe. Part 1. Theory and instrumentation.基于磷光寿命猝灭并采用聚合物固定化金属卟啉探针的光学氧传感器。第1部分。理论与仪器。

本文引用的文献

1
Optical oxygen sensor based on phosphorescence lifetime quenching and employing a polymer immobilised metalloporphyrin probe. Part 1. Theory and instrumentation.基于磷光寿命猝灭并采用聚合物固定化金属卟啉探针的光学氧传感器。第1部分。理论与仪器。
Med Biol Eng Comput. 1993 Jan;31(1):2-10. doi: 10.1007/BF02446879.
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Fiber-optic probe for in vivo measurement of oxygen partial pressure.
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Med Biol Eng Comput. 1990 May;28(3):B34-47. doi: 10.1007/BF02442679.
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Respir Physiol. 1978 Oct;35(1):89-99. doi: 10.1016/0034-5687(78)90044-0.