Minguillón C, Franco P, Oliveros L, López P
Laboratori de Química Farmacèutica, Facultat de Farmàcia, Universitat de Barcelona, Spain.
J Chromatogr A. 1996 Mar 29;728(1-2):407-14. doi: 10.1016/0021-9673(95)01123-4.
Four mixed 10-undecenoyl-3,5-dimethylphenylaminocarbonyl derivatives of cellulose, with an increasing proportion of alkenoyl groups, were synthesized and chemically bonded on allylsilica gel. The influence of the degree of fixation of the cellulose derivative on the matrix for the four resulting chiral stationary phases on their selectivity is discussed.
合成了四种纤维素的混合10-十一碳烯酰-3,5-二甲基苯基氨基甲酰基衍生物，其烯酰基比例逐渐增加，并将它们化学键合到烯丙基硅胶上。讨论了纤维素衍生物在基质上的固定程度对所得四种手性固定相选择性的影响。
