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气相色谱-质谱法测定水果和蔬菜中的单环芳烃

Determination of monocyclic aromatic hydrocarbons in fruit and vegetables by gas chromatography-mass spectrometry.

作者信息

Górna-Binkul A, Keymeulen R, Van Langenhove H, Buszewski B

机构信息

Department of Environmental Chemistry, Faculty of Chemistry, Nicholas Copernicus University, Toruń, Poland.

出版信息

J Chromatogr A. 1996 May 24;734(2):297-302. doi: 10.1016/0021-9673(96)00038-6.

Abstract

Monocylic aromatic hydrocarbons (MAHs: benzene, toluene, ehtylbenzene and xylenes) were isolated from fruit and vegetables using a solvent extraction technique. GC-MS (with selected-ion monitoring mode) was applied for determination of the isolated pollutants. It was observed that uptake of MAHs depends on the species and takes place in different morphological parts of the biological material. The highest concentrations of MAHs were found in parsley leaves (m- and p-xylene) and in orange peel (toluene). Estimation of the daily human exposure to MAHs through eating contaminated fruit and vegetables was performed.

摘要

采用溶剂萃取技术从水果和蔬菜中分离出单环芳烃(MAHs:苯、甲苯、乙苯和二甲苯)。运用气相色谱-质谱联用仪(采用选择离子监测模式)测定分离出的污染物。结果发现,单环芳烃的吸收取决于物种,且发生在生物材料的不同形态部位。在欧芹叶(间二甲苯和对二甲苯)和橙皮(甲苯)中发现了最高浓度的单环芳烃。对通过食用受污染的水果和蔬菜导致的人类每日单环芳烃暴露量进行了估算。

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