来自秦岭翠雀花的二萜生物碱。
Diterpenoid alkaloids from Delphinium davisii.
作者信息
Ulubelen A, Desai H K, Srivastava S K, Hart B P, Park J C, Joshi B S, Pelletier S W, Meriçli A H, Meriçli F, Ilarslan R
机构信息
Faculty of Pharmacy, University of Istanbul, Turkey.
出版信息
J Nat Prod. 1996 Apr;59(4):360-6. doi: 10.1021/np960215f.
Three new hetisane-type diterpenoid alkaloids, davisinol (6), 18-benzoyldavisinol (7), and Davisin (9) have been isolated from Delphinium davisii Munz. and their structures established by detailed spectroscopic studies. Accurate 1H- and 13C-NMR assignments have been made for kobusine (8), a related hetisane-type alkaloid, and karakoline (5), a norditerpenoid alkaloid. The known norditerpenoid alkaloids 14-acetylperegrine (4), 6-deacetylperegrine (3), and karakoline (5) and the diterpenoid alkaloids hetisine and hetisinone were also isolated.
从戴维斯翠雀花（Delphinium davisii Munz）中分离出了三种新的海替烷型二萜生物碱，即达维索醇（6）、18-苯甲酰基达维索醇（7）和达维辛（9），并通过详细的光谱研究确定了它们的结构。已对相关的海替烷型生物碱考布辛（8）和去甲二萜生物碱卡拉可林（5）进行了精确的¹H-和¹³C-NMR归属。还分离出了已知的去甲二萜生物碱14-乙酰基百瑞灵（4）、6-脱乙酰基百瑞灵（3）和卡拉可林（5）以及二萜生物碱海替辛和海替辛酮。
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