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来自凹叶胡椒的杀虫新木脂素。

Insecticidal neolignans from Piper decurrens.

作者信息

Chauret D C, Bernard C B, Arnason J T, Durst T, Krishnamurty H G, Sanchez-Vindas P, Moreno N, Roman L S, Poveda L

机构信息

Department of Chemistry, University of Ottawa, Canada.

出版信息

J Nat Prod. 1996 Feb;59(2):152-5. doi: 10.1021/np960036y.

DOI:10.1021/np960036y
PMID:8991948
Abstract

2,3-Dihydro-2-(4'-hydroxyphenyl)-3-methyl-5(E)-propenylbenzofuran (conocarpan) (1), 2-(4'-hydroxy-3'-methoxyphenyl)-3-methyl-5(E)- propenylbenzofuran (eupomatenoid-5) (2), and 2-(4'- hydroxyphenyl)-3-methyl-5(E)-propenylbenzofuran (eupomatenoid-6) (3), three known neolignans found for the first time in a species of the Piperaceae, were isolated from Piper decurrens via insecticidal bioassay-guided fractionation, along with a small quantity of a new related compound, 2,3-dihydro-5-formyl-2-(4'-hydroxyphenyl)-3-methylbenzofuran (decurrenal) (4), and 3,7,11,15-tetramethyl-2(E)-hexadecen-1-ol (trans-phytol).

摘要

2,3-二氢-2-(4'-羟基苯基)-3-甲基-5(E)-丙烯基苯并呋喃(柯诺卡潘)(1)、2-(4'-羟基-3'-甲氧基苯基)-3-甲基-5(E)-丙烯基苯并呋喃(优波马替诺-5)(2)和2-(4'-羟基苯基)-3-甲基-5(E)-丙烯基苯并呋喃(优波马替诺-6)(3),这三种首次在胡椒科某一物种中发现的已知新木脂素,是通过杀虫生物测定引导的分级分离法从垂穗胡椒中分离得到的,同时还得到了少量新的相关化合物2,3-二氢-5-甲酰基-2-(4'-羟基苯基)-3-甲基苯并呋喃(垂穗胡椒醛)(4)和3,7,11,15-四甲基-2(E)-十六碳烯-1-醇(反式叶绿醇)。

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