Jacobs R E, Hudson B S, Andersen H C
Biochemistry. 1977 Oct 4;16(20):4349-59. doi: 10.1021/bi00639a004.
A statistical mechanical partition function for phospholipid bilayers is constructed to obtain a theoretical description of the chain melting phase transition in lipid bilayer membranes and of the phase diagrams for two-component bilayers. In addition to providing an accurate representation of the transition temperatures and enthalpies of one-component bilayers composed of 1,2-diacylphosphatidylcholines, the theory can also account for the shapes of the phase diagrams observed for bilayers which are binary mixtures of these compounds with two different hydrocarbon chain lenghts.
构建了一个用于磷脂双层的统计力学配分函数，以获得脂质双层膜中链熔化相变以及双组分双层相图的理论描述。除了能准确表示由1,2 - 二酰基磷脂酰胆碱组成的单组分双层的转变温度和焓外，该理论还能解释这些化合物与两种不同烃链长度的二元混合物双层所观察到的相图形状。
