固相有机合成（SPOS）中的偶极环加成反应。
Dipolar cycloadditions in solid-phase organic synthesis (SPOS).
作者信息
Kantorowski E J, Kurth M J
机构信息
Department of Chemistry, University of California, Davis 95616, USA.
出版信息
Mol Divers. 1997;2(4):207-16. doi: 10.1007/BF01715636.
PMID:9249756
Abstract
We present a concise review of polymer-supported 1,3-dipolar cycloaddition reactions. Nitrile oxide and azomethine ylides constitute the two types of 1,3-dipoles which have been used in conjunction with solid-phase organic synthesis. These cycloaddition reactions on solid phase are generally of equal or greater efficiency than the analogous solution-phase reactions.
摘要
我们对聚合物负载的1,3-偶极环加成反应进行简要综述。氧化腈和甲亚胺叶立德是两类已与固相有机合成结合使用的1,3-偶极体。这些固相环加成反应通常比类似的溶液相反应具有相同或更高的效率。
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