Saleh M A, Kamel A, el-Demerdash A, Jones J
Department of Chemistry, Texas Southern University, Houston 77004, USA.
Chemosphere. 1998 Mar;36(7):1543-52. doi: 10.1016/s0045-6535(97)10052-2.
Six different types of fabrics were compared for their ability to protect against human exposure to three different commercial household aerosol insecticides. Fabrics used in this investigation were, 100% cotton, cotton-polyester thermal underwear, cotton-polyester blend (twill), 100% acrylic, 100% wool and artificial silk (rayon). The household insecticides were, Black Flag (Ant and Roach Killer), Raid (Ant and Roach Killer) and Hot Shot (Wasp and Hornet Killer) containing propoxur, permethrin/pyrethrins and chlorpyrifos/allethrins as their active ingredients respectively. A fluorescent tracer, 4-methyl-7-diethyl amino coumarin was mixed with the aerosol (or equivalent aliquot) and sprayed onto cloth squares fitted on Whatman paper patches. The percentage of penetration through the cloth was quantified by the intensity of the fluorescence spectrum of each patch extract and the amount of the tracer recovered was calculated. The extract was concentrated to 1/10th of the volume to measure the content of each of the insecticides by supercritical fluid chromatography (SFC) using electron capture (ECD) and diode array detectors. Scanning electron microscope (SEM) images of the fabrics showed the geometry of the yarn. The results obtained from the fluorescence spectra, SFC and SEM showed that cotton-polyester (twill), cotton, wool and cotton thermal underwear were the least penetrable materials for the aerosols. On the other hand, acrylic and artificial silk (rayon) were the most penetrable cloth types.
对六种不同类型的织物进行了比较,以评估它们对人类接触三种不同商用家用气雾剂杀虫剂的防护能力。本研究中使用的织物有100%棉、棉涤保暖内衣、棉涤混纺(斜纹布)、100%腈纶、100%羊毛和人造丝(嫘萦)。家用杀虫剂分别是黑旗(蚂蚁和蟑螂杀手)、雷达(蚂蚁和蟑螂杀手)和热射(黄蜂和大黄蜂杀手),其活性成分分别为残杀威、氯菊酯/除虫菊酯和毒死蜱/丙烯菊酯。将一种荧光示踪剂4-甲基-7-二乙氨基香豆素与气雾剂(或等量试样)混合,喷洒在装在沃特曼纸贴片上的布方块上。通过每个贴片提取物荧光光谱的强度对透过布料的穿透百分比进行定量,并计算回收的示踪剂的量。将提取物浓缩至体积的1/10,使用电子捕获(ECD)和二极管阵列检测器,通过超临界流体色谱(SFC)测量每种杀虫剂的含量。织物的扫描电子显微镜(SEM)图像显示了纱线的几何形状。从荧光光谱、SFC和SEM获得的结果表明,棉涤(斜纹布)、棉、羊毛和棉涤保暖内衣是对气雾剂穿透性最小的材料。另一方面,腈纶和人造丝(嫘萦)是穿透性最强的布料类型。