The development of an improved method for the determination of coal tar pitch volatiles (CTPV) in air.

Test samples were collected at a range of sites using the MDHS 68 sampler, a 7-hole sampler, and a cyclone respirable-dust sampler. Glass fibre, Zefluor, Fluoropore and silver (0.8 and 5 microns) filters were compared for weighing error, handling characteristics, and amount collected. The effects of a carbon back-up, of extraction solvent, and of analytical method were studied. The current HSE method for the sampling and analysis of coal tar pitch volatiles, MDHS 68 has been reviewed. It is recommended that the MDHS 68 sampler be replaced by a 7-hole head containing a silver or PTFE filter (approximately 1 micron pore size), with a graphitized carbon back-up if efficient collection of 2 to 4-ring PAHs is required. Cyclohexane is recommended as the extraction solvent. Methods of analysis which quantify the fume as a whole (MDHS 68, u.v., ELSD) were shown to give a response which varied according to the type of CTPV generating process. Therefore analysis of specific PAHs of occupational interest, by GC-MS or HPLC is recommended.