Foster K R, Resing H A, Garroway A N
Science. 1976 Oct 15;194(4262):324-6. doi: 10.1126/science.968484.
Relatively mobile protons that do not exchange with D2O exist in barnacle muscle cells. These are not part of the nonfreezing "bound water" that does exchange. Ninety-seven percent of the muscle water exhibits a single transverse relaxation time of 35 milliseconds: one water molecule per thousand, which is briefly and irrotationally bound, will produce the observed relaxation properties.