Tenaglia A, Heumann A
Université d'Aix-Marseille, Faculté de St-Jérôme, ENSSPICAM, UMR-CNRS 6516, F 13397 Marseille Cedex 20 (France).
Angew Chem Int Ed Engl. 1999 Aug;38(15):2180-2184.
Many palladium-catalyzed organic reactions with tailored ligands, besides the princess of asymmetric catalysis, allylic alkylation, are suitable for enantioselective organic synthesis. This is clearly illustrated by the large number of promising examples such as the Heck reaction, and Wacker-type oxidations, cycloadditions, cycloisomerizations, carbonylations, and copolymerization of alkenes with carbon monoxide.
除了不对称催化的“公主”——烯丙基烷基化反应外，许多使用定制配体的钯催化有机反应也适用于对映选择性有机合成。大量有前景的例子清楚地说明了这一点，比如Heck反应、瓦克型氧化反应、环加成反应、环异构化反应、羰基化反应以及烯烃与一氧化碳的共聚反应。
